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基于淀粉浆料的可持续光催化退浆工艺

Sustainable Photocatalytic Desizing Process for the Starch-Based Size.

作者信息

Panda Sanjay Kumar Bhikari Charan, Sen Kushal, Mukhopadhyay Samrat

机构信息

Department of Textile and Fibre Engineering, Indian Institute of Technology Delhi, New Delhi 110016, India.

出版信息

ACS Omega. 2023 May 15;8(21):18726-18734. doi: 10.1021/acsomega.3c00713. eCollection 2023 May 30.

Abstract

Textile wet processing highly impacts the environment due to its massive water and energy consumption. High consumption of water also results in the generation of a considerable volume of effluents. In this regard, an ultraviolet C (UVC)-assisted desizing method of starch-sized cotton fabric has been developed to lower the utility consumption in textile pretreatment. A UVC cabinet is designed to control exposing temperature and energy of exposure on the starch-sized cotton fabric. The UVC exposure time is optimized concerning the desizing efficiency. The UVC-exposed-sized fabric is washed with different washing times and washing temperatures to optimize the process. The alkali consumption in washing is reduced by 75% and desizing efficiency is improved to 95%. The application of oxidizing agents like NaNO, KSO, and NaBO·4HO during sizing further reduced the washing temperature and washing time for desizing to obtain 100% desizing efficiency. The UVC-assisted desized fabric is characterized by the whiteness index, water absorbency, tensile strength, Fourier transform infrared (FTIR), and wide-angle X-ray diffraction and compared with the control. The UVC-assisted desizing process has the potential to save approximately 60% water, 90% energy, and more than 70% of the time. Life cycle analysis has also been done. The photocatalytic desizing process can reduce the impact on human health by more than 85% and save approximately 69% of mineral resources than the conventional technique. The textile industry can quickly adopt a novel approach for sustainable desizing.

摘要

纺织品湿加工因其大量的水和能源消耗而对环境产生重大影响。高耗水量还导致产生大量废水。在这方面,已开发出一种紫外线C(UVC)辅助的淀粉上浆棉织物退浆方法,以降低纺织品预处理中的公用事业消耗。设计了一个UVC箱来控制淀粉上浆棉织物的暴露温度和暴露能量。针对退浆效率优化了UVC暴露时间。对经UVC照射的上浆织物进行不同洗涤时间和洗涤温度的洗涤以优化该工艺。洗涤中的碱消耗量减少了75%,退浆效率提高到了95%。在上浆过程中应用NaNO、KSO和NaBO·4HO等氧化剂进一步降低了退浆的洗涤温度和洗涤时间,以获得100%的退浆效率。通过白度指数、吸水性、拉伸强度、傅里叶变换红外光谱(FTIR)和广角X射线衍射对UVC辅助退浆织物进行表征,并与对照进行比较。UVC辅助退浆工艺有可能节省约60%的水、90%的能源和70%以上的时间。还进行了生命周期分析。与传统技术相比,光催化退浆工艺可将对人类健康的影响降低85%以上,并节省约69%的矿产资源。纺织行业可以迅速采用一种新颖的可持续退浆方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dda0/10233833/783df66210b6/ao3c00713_0002.jpg

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