State Key Laboratory of Microbial Technology, Institute of Microbial Technology, Shandong University, No. 72 Binhai Avenue, Qingdao, 266237, P. R. China.
Suzhou Institute of Shandong University, No. 388 Ruoshui Road, Suzhou Industrial Park, Suzhou, 215123, P. R. China.
Org Lett. 2023 Jun 23;25(24):4576-4580. doi: 10.1021/acs.orglett.3c01642. Epub 2023 Jun 8.
We report, herein, a photoinduced iron-catalyzed direct chlorination of aromatic sulfonyl chloride at room temperature. In this protocol, FeCl-catalyzed direct chlorination has been realized at room temperature under the irradiation of light (400-410 nm). During the process, many commercially or readily available substituted aromatic sulfonyl chlorides could produce the corresponding aromatic chlorides in moderate to good yields.
我们在此报告了一种在室温下光诱导铁催化的芳基磺酰氯的直接氯化反应。在该方案中，在光（400-410nm）照射下，实现了 FeCl 催化的室温直接氯化。在这个过程中，许多商业上或容易获得的取代芳基磺酰氯可以中等至良好的产率得到相应的芳基氯化物。
