Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, People's Republic of China; Jinkai Instrument (Dalian) Company Limited, People's Republic of China.
Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, People's Republic of China.
Talanta. 2023 Nov 1;264:124763. doi: 10.1016/j.talanta.2023.124763. Epub 2023 Jun 4.
Peroxide-based explosives (PBEs) are increasingly common in criminal and terrorist activity due to their easy synthesis and high explosive power. The rise in terrorist attacks involving PBEs has heightened the importance of detecting trace amounts of explosive residue or vapors. This paper aims to provide a review on the developments of techniques and instruments for detecting PBEs over the past ten years, specifically discussing advancements in ion mobility spectrometry, ambient mass spectrometry, fluorescence techniques, colorimetric methods, and electrochemical methods. We provide examples to illustrate their evolution and focus on new strategies for improving detection performance, specifically in terms of sensitivity, selectivity, high-throughput, and wide explosives coverage. Finally, we discuss future prospects for PBE detection. It is hoped this treatment will serve as a guide to the novitiate and as aid memoire to the researchers.
基于过氧化物的爆炸物(PBEs)由于其易于合成和高爆炸威力,在犯罪和恐怖活动中越来越常见。涉及 PBE 的恐怖袭击的增加,提高了检测痕量爆炸残留物或蒸气的重要性。本文旨在综述过去十年中用于检测 PBE 的技术和仪器的发展,特别讨论了离子淌度谱、环境质谱、荧光技术、比色法和电化学方法的进展。我们提供了一些例子来说明它们的演变,并重点介绍了提高检测性能的新策略,特别是在灵敏度、选择性、高通量和广泛的爆炸物覆盖范围方面。最后,我们讨论了 PBE 检测的未来前景。希望本综述能为初学者提供指导,并为研究人员提供参考。