Sitepu Eko K, Perangin-Angin Sabarmin, Ginting Gloria J, Machmudah Siti, Sari Rodiah N, Tarigan Juliati Br
Department of Chemistry, Universitas Sumatera Utara, Medan 20155, Indonesia.
Department of Chemical Engineering, Institut Teknologi Sepuluh Nopember, Surabaya 60111, Indonesia.
Heliyon. 2023 May 27;9(6):e16402. doi: 10.1016/j.heliyon.2023.e16402. eCollection 2023 Jun.
Insect larvae contain sufficient oil comparable with oleaginous biomass, and hence have potency as alternative biodiesel resources. The direct transesterification of Black Soldier Fly (BSF) larvae have conducted using a controllable crushing device (CCD) and a homogeneous base as a catalyst. The effect of catalyst concentration (wt.%), ratio BSF larvae to methanol (wt./v), reaction time (min) and rotational speed (rpm) on biodiesel conversion was determined. The maximum conversion of 93.8% was achieved at room temperature after 20 min of reaction time and ratio larvae to methanol of 1:2 (wt./v), catalyst concentration of 7 wt% and rotational speed of 3000 rpm. In addition, the green metrics calculation showed that this method produces less waste and uses less solvent. Some of the BSF-biodiesel properties meet the biodiesel standard. The CCD-intensified the DT of BSF larvae is a promising alternative for green and energy-saved biodiesel production.
昆虫幼虫含有与含油生物质相当的足够油脂,因此有潜力作为替代生物柴油资源。已使用可控粉碎装置(CCD)和均相碱作为催化剂对黑水虻(BSF)幼虫进行直接酯交换反应。测定了催化剂浓度(重量%)、BSF幼虫与甲醇的比例(重量/体积)、反应时间(分钟)和转速(转/分钟)对生物柴油转化率的影响。在室温下,反应20分钟后,幼虫与甲醇的比例为1:2(重量/体积)、催化剂浓度为7重量%、转速为3000转/分钟时,实现了93.8%的最大转化率。此外,绿色指标计算表明,该方法产生的废物更少,使用的溶剂更少。一些BSF生物柴油的性能符合生物柴油标准。CCD强化的BSF幼虫直接酯交换反应是绿色节能生物柴油生产的一种有前景的替代方法。