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综述 ZnO/CdS 异质结构光催化剂在降解有机污染物和制氢方面的最新制备进展。

Review of Recent Developments in the Fabrication of ZnO/CdS Heterostructure Photocatalysts for Degradation of Organic Pollutants and Hydrogen Production.

机构信息

Chemistry Division, Department of Basic Sciences and Humanities, GMR Institute of Technology, Rajam 532127, Andhra Pradesh, India.

Department of Mechanical Engineering, GMR Institute of Technology, Rajam 532127, Andhra Pradesh, India.

出版信息

Molecules. 2023 May 23;28(11):4277. doi: 10.3390/molecules28114277.

Abstract

Researchers have recently paid a lot of attention to semiconductor photocatalysts, especially ZnO-based heterostructures. Due to its availability, robustness, and biocompatibility, ZnO is a widely researched material in the fields of photocatalysis and energy storage. It is also environmentally beneficial. However, the wide bandgap energy and quick recombination of the photoinduced electron-hole pairs of ZnO limit its practical utility. To address these issues, many techniques have been used, such as the doping of metal ions and the creation of binary or ternary composites. Recent studies showed that ZnO/CdS heterostructures outperformed bare ZnO and CdS nanostructures in terms of photocatalytic performance when exposed to visible light. This review largely concentrated on the ZnO/CdS heterostructure production process and its possible applications including the degradation of organic pollutants and hydrogen evaluation. The importance of synthesis techniques such as bandgap engineering and controlled morphology was highlighted. In addition, the prospective uses of ZnO/CdS heterostructures in the realm of photocatalysis and the conceivable photodegradation mechanism were examined. Lastly, ZnO/CdS heterostructures' challenges and prospects for the future have been discussed.

摘要

研究人员最近对半导体光催化剂,特别是基于 ZnO 的异质结构给予了高度关注。由于 ZnO 具有可用性、坚固性和生物相容性,因此在光催化和储能领域得到了广泛的研究。此外,它还对环境有益。然而,ZnO 光致电子空穴对的宽能带隙能量和快速复合限制了其实际应用。为了解决这些问题,已经采用了许多技术,例如金属离子掺杂和二元或三元复合材料的制备。最近的研究表明,在可见光照射下,ZnO/CdS 异质结构在光催化性能方面优于裸露的 ZnO 和 CdS 纳米结构。本综述主要集中在 ZnO/CdS 异质结构的制备工艺及其可能的应用,包括有机污染物的降解和氢气评价。强调了诸如能带工程和控制形态等合成技术的重要性。此外,还研究了 ZnO/CdS 异质结构在光催化领域的潜在应用以及可能的光降解机制。最后,讨论了 ZnO/CdS 异质结构的挑战和未来展望。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2cea/10254503/066851e2b587/molecules-28-04277-g001.jpg

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