Hang Le Thuy, Do Quoc-Viet, Hoang Luu, Nguyen Luc The, Linh Nguyen Pham Duy, Doan Vu Anh
Faculty of Garment Technology and Fashion Design, Hung Yen University of Technology and Education, Hung Yen 160000, Vietnam.
School of Material Science, Japan Advanced Institute of Science and Technology, 1-1 Asahidai, Ishikawa, Nomi 923-1292, Japan.
Polymers (Basel). 2023 May 25;15(11):2453. doi: 10.3390/polym15112453.
This study aimed to improve the mechanical properties of a composite material consisting of waste leather fibers (LF) and nitrile rubber (NBR) by partially replacing LF with waste polyamide fibers (PA). A ternary recycled composite NBR/LF/PA was produced by a simple mixing method and vulcanized by compression molding. The mechanical properties and dynamic mechanical properties of the composite were investigated in detail. The results showed that the mechanical properties of NBR/LF/PA increased with an increase in the PA ratio. The highest tensile strength value of NBR/LF/PA was found to have increased about 1.26 times, that is from 12.9 MPa of LF50 to 16.3 MPa of LF25PA25. Additionally, the ternary composite demonstrated high hysteresis loss, which was confirmed by dynamic mechanical analysis (DMA). The presence of PA formed a non-woven network that significantly enhanced the abrasion resistance of the composite compared to NBR/LF. The failure mechanism was also analyzed through the observation of the failure surface using scanning electron microscopy (SEM). These findings suggest that the utilization of both waste fiber products together is a sustainable approach to reducing fibrous waste while improving the qualities of recycled rubber composites.
本研究旨在通过用废聚酰胺纤维(PA)部分替代废皮革纤维(LF)来改善由废皮革纤维和丁腈橡胶(NBR)组成的复合材料的力学性能。通过简单的混合方法制备了三元回收复合材料NBR/LF/PA,并通过模压硫化。详细研究了该复合材料的力学性能和动态力学性能。结果表明,NBR/LF/PA的力学性能随着PA比例的增加而提高。发现NBR/LF/PA的最高拉伸强度值增加了约1.26倍,即从LF50的12.9MPa增加到LF25PA25的16.3MPa。此外,通过动态力学分析(DMA)证实,该三元复合材料表现出高滞后损耗。PA的存在形成了一个非织造网络,与NBR/LF相比,显著提高了复合材料的耐磨性。还通过使用扫描电子显微镜(SEM)观察破坏表面来分析破坏机制。这些发现表明,同时利用这两种废纤维产品是一种可持续的方法,既能减少纤维废料,又能提高回收橡胶复合材料的质量。