开关一个 Au(I)-Pb(II) 配合物中的溶剂配位：高压和高温作为外部刺激。
Switching On/Off of a Solvent Coordination in a Au(I)-Pb(II) Complex: High Pressure and Temperature as External Stimuli.
机构信息
Departamento de Química, Centro de Investigación en Síntesis Química (CISQ), Complejo Científico-Tecnológico, Universidad de La Rioja, 26006 Logroño, Spain.
Laboratory for Synchrotron Radiation-Condensed Matter, Paul Scherrer Institute (PSI), WLGA/229 Forschungsstrasse 111, 5232 Villigen, Switzerland.
出版信息
Inorg Chem. 2023 Jul 3;62(26):10307-10316. doi: 10.1021/acs.inorgchem.3c01130. Epub 2023 Jun 16.
The benzonitrile solvate {[{Au(CF)}{Pb(terpy)}]·NCPh} () (terpy = 2,2':6',2″-terpyridine) displays reversible reorientation and coordination of the benzonitrile molecule to lead upon external stimuli. High-pressure X-ray diffraction studies between 0 and 2.1 GPa reveal a 100% of conversion without loss of symmetry, which is totally reversible upon decompression. By variable-temperature X-ray diffraction studies between 100 and 285 K, a partial coordination is achieved.
苯甲腈溶剂化物{[{Au(CF)}(Pb(terpy))]·NCPh}()]（terpy = 2,2':6',2″-三联吡啶）在外力刺激下可实现苯甲腈分子的可逆取向和配位。在 0 至 2.1 GPa 之间的高压 X 射线衍射研究表明，在不损失对称性的情况下，转化率达到 100%，且在减压时完全可逆。通过在 100 至 285 K 之间的变温 X 射线衍射研究，实现了部分配位。
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