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高压下金属有机框架的结构研究

Structural studies of metal-organic frameworks under high pressure.

作者信息

McKellar Scott C, Moggach Stephen A

机构信息

EaStCHEM School of Chemistry and the Centre for Science at Extreme Conditions, University of Edinburgh, Kings Buildings, West Mains Road, Edinburgh EH9 3JJ, Scotland.

出版信息

Acta Crystallogr B Struct Sci Cryst Eng Mater. 2015 Dec 1;71(Pt 6):587-607. doi: 10.1107/S2052520615018168. Epub 2015 Nov 7.

DOI:10.1107/S2052520615018168
PMID:26634716
Abstract

Over the last 10 years or so, the interest and number of high-pressure studies has increased substantially. One area of growth within this niche field is in the study of metal-organic frameworks (MOFs or coordination polymers). Here we present a review on the subject, where we look at the structural effects of both non-porous and porous MOFs, and discuss their mechanical and chemical response to elevated pressures.

摘要

在过去大约10年里,高压研究的关注度和数量大幅增加。这个细分领域内的一个增长领域是金属有机框架(MOF或配位聚合物)的研究。在此,我们对该主题进行综述,探讨无孔和多孔MOF的结构效应,并讨论它们在高压下的力学和化学反应。

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