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山油柑碱的化学,十二。降山油柑碱的进一步低聚物。

Chemistry of acronycine, XII. Further oligomers of noracronycine.

作者信息

Funayama S, Cordell G A

出版信息

J Nat Prod. 1986 Mar-Apr;49(2):210-7. doi: 10.1021/np50044a003.

Abstract

The polymerization of noracronycine (2) with methanolic HCl has yielded a second tetramer of 2, designated as AB-4 and determined to have the structure 7 through spectroscopic analysis. Two further pentamers of 2, designated as AB-6A and AB-6B, have also been obtained, and their structures are tentatively proposed as 9 and 5, respectively.

摘要

去甲克罗尼辛(2)与甲醇盐酸聚合反应生成了2的另一种四聚体,命名为AB - 4,并通过光谱分析确定其结构为7。还得到了2的另外两种五聚体,分别命名为AB - 6A和AB - 6B,其结构暂定为分别为9和5。

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