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一种包含石墨烯和钛酸钡层的表面等离子体共振纳米结构,用于有机化合物的灵敏检测。

A surface plasmon resonance nanostructure containing graphene and BaTiO layers for sensitive defection of organic compounds.

作者信息

Taya Sofyan A, Daher Malek G, Almawgani Abdulkarem H M, Hindi Ayman Taher, Colak Ilhami

机构信息

Physics Department, Islamic University of Gaza, P.O. Box 108, Gaza, Palestine.

Electrical Engineering Department, College of Engineering, Najran University, Najran, Kingdom of Saudi Arabia.

出版信息

R Soc Open Sci. 2023 Jun 21;10(6):230282. doi: 10.1098/rsos.230282. eCollection 2023 Jun.

Abstract

Organic compound-based sensors are used in a variety of significant fields, including medical research, azeotropic calibration, vegetable oil extraction, the shoe industry and geothermal power plants. Here, a high-performance, two-dimensional material-based organic compound sensor has been proposed using a surface plasmon resonance (SPR) nanostructure consisting of a BK7 glass prism, Ag, BaTiO, Ag, graphene and sensing layer. The reflectivity curves of the SPR device have been investigated when the sensing media are Pentane, n-Hexane, n-Heptane and n-Octane. The thickness of the BaTiO layer and the number of graphene sheets have been optimized to maximize the sensitivity. The highest sensitivity attained is 220.83 deg/RIU for n-Octane with 45 nm silver/10 nm BaTiO/8 nm silver and four layers of graphene. We believe that the SPR-based sensors are simple and can replace the spectrometry, chromatography and electrochemical based sensors. The proposed design is extremely effective for diverse applications in biological, industrial and chemical detection because of its simple structure and great performance.

摘要

基于有机化合物的传感器被应用于各种重要领域,包括医学研究、共沸校准、植物油提取、制鞋工业和地热发电厂。在此,利用由BK7玻璃棱镜、银、钛酸钡、银、石墨烯和传感层组成的表面等离子体共振(SPR)纳米结构,提出了一种高性能的基于二维材料的有机化合物传感器。当传感介质为戊烷、正己烷、正庚烷和正辛烷时,研究了SPR器件的反射率曲线。优化了钛酸钡层的厚度和石墨烯片的数量,以实现灵敏度最大化。对于45nm银/10nm钛酸钡/8nm银和四层石墨烯的结构,正辛烷的最高灵敏度达到220.83度/RIU。我们认为基于SPR的传感器结构简单,可替代基于光谱法、色谱法和电化学的传感器。由于其结构简单和性能优异,所提出的设计对于生物、工业和化学检测中的各种应用极为有效。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6a1f/10282577/8f3ba3baad3d/rsos230282f01.jpg

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