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用于能源应用的钙钛矿启发型材料。

Perovskite-inspired materials for energy applications.

作者信息

Hoye Robert L Z

机构信息

Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford OX1 3QR, United Kingdom.

出版信息

Nanotechnology. 2023 Jul 24;34(41). doi: 10.1088/1361-6528/ace171.

Abstract

Lead-halide perovskites have come to dominate the emerging photovoltaics research scene over the past decade. But whilst perovskite photovoltaics exhibit exceptional efficiencies, their limited stability, as well as the toxicity of their lead component remain challenges. This focus collection captures a snapshot of the efforts in the community to address these challenges, from modifications to the synthesis and device structure of perovskite photovoltaics to improve their stability, through to efforts to understand, develop, and improve lead-free perovskite-inspired materials (PIMs). PIMs range from direct perovskite-derivatives (e.g. CsSnIor halide elpasolites) through to electronic analogs (e.g. BiOI). The collection discusses the application of these materials not only for solar cells, but also more broadly for photodetection, light emission, and anti-counterfeiting devices. This collection emphasizes the diversity of strategies and directions in this field, as well as its highly interdisciplinary nature.

摘要

在过去十年中,卤化铅钙钛矿已在新兴的光伏研究领域占据主导地位。然而,尽管钙钛矿光伏电池展现出卓越的效率,但其稳定性有限以及铅成分具有毒性,仍然是挑战。本专题文集呈现了该领域为应对这些挑战所做努力的一个缩影,从对钙钛矿光伏电池的合成和器件结构进行改性以提高其稳定性,到致力于理解、开发和改进无铅钙钛矿启发材料(PIMs)。PIMs的范围从直接的钙钛矿衍生物(如CsSnI或卤化物埃尔帕索石)到电子类似物(如BiOI)。该文集不仅讨论了这些材料在太阳能电池中的应用,还更广泛地探讨了其在光探测、发光和防伪器件中的应用。本专题文集强调了该领域策略和方向的多样性,以及其高度跨学科的性质。

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