Jiao Zhibin, Wang Ze, Wang Zhaozhi, Han Zhiwu
Key Laboratory of Bionic Engineering, Ministry of Education, Jilin University, Changchun 130022, China.
School of Mechanical Engineering, Shenyang University of Technology, Shenyang 110870, China.
Nanomaterials (Basel). 2023 Jun 13;13(12):1855. doi: 10.3390/nano13121855.
Antireflective and self-cleaning coatings have attracted increasing attention in the last few years due to their promising and wider applications such as stealth, display devices, sensing, and other fields. However, existing antireflective and self-cleaning functional material are facing problems such as difficult performance optimization, poor mechanical stability, and poor environmental adaptability. Limitations in design strategies have severely restricted coatings' further development and application. Fabrication of high-performance antireflection and self-cleaning coatings with satisfactory mechanical stability remain a key challenge. Inspired by the self-cleaning performance of nano-/micro-composite structure on natural lotus leaves, SiO/PDMS/matte polyurethane biomimetic composite coating (BCC) was prepared by nano-polymerization spraying technology. The BCC reduced the average reflectivity of the aluminum alloy substrate surface from 60% to 10%, and the water contact angle (CA) was 156.32 ± 0.58°, illustrating the antireflective and self-cleaning performance of the surface was significantly improved. At the same time, the coating was able to withstand 44 abrasion tests, 230 tape stripping tests, and 210 scraping tests. After the test, the coating still showed satisfactory antireflective and self-cleaning properties, indicating its remarkable mechanical stability. In addition, the coating also displayed excellent acid resistance, which has important value in aerospace, optoelectronics, industrial anti-corrosion, etc.
抗反射和自清洁涂层在过去几年中受到了越来越多的关注,因为它们在隐身、显示设备、传感等领域有着广阔的应用前景。然而,现有的抗反射和自清洁功能材料面临着性能优化困难、机械稳定性差和环境适应性差等问题。设计策略的局限性严重制约了涂层的进一步发展和应用。制备具有令人满意机械稳定性的高性能抗反射和自清洁涂层仍然是一个关键挑战。受天然荷叶上纳米/微复合结构自清洁性能的启发,通过纳米聚合喷涂技术制备了SiO/PDMS/哑光聚氨酯仿生复合涂层(BCC)。BCC将铝合金基体表面的平均反射率从60%降低到10%,水接触角(CA)为156.32±0.58°,表明表面的抗反射和自清洁性能得到了显著改善。同时,该涂层能够承受44次磨损试验、230次胶带剥离试验和210次刮擦试验。试验后,涂层仍表现出令人满意的抗反射和自清洁性能,表明其具有卓越的机械稳定性。此外,该涂层还表现出优异的耐酸性,在航空航天、光电子、工业防腐等领域具有重要价值。