Muñoz-Blandón Oscar, Ramírez-Carmona Margarita, Rendón-Castrillón Leidy, Ocampo-López Carlos
Centro de Estudios y de Investigación en Biotecnología (CIBIOT), Chemical Engineering Faculty, Universidad Pontificia Bolivariana, Medellín 050031, Colombia.
Polymers (Basel). 2023 Jun 17;15(12):2712. doi: 10.3390/polym15122712.
Many studies available in the literature focus mainly on the mechanical characterization of fiber, leaving out other physicochemical and thermogravimetric analyses that allow for establishing its potential as an engineering material. This study characterizes fique fiber for its potential use as an engineering material. The fiber's chemical composition and physical, thermal, mechanical, and textile properties were analyzed. The fiber has a high holocellulose content and low lignin and pectin content, indicating its potential as a natural composite material for various applications. Infrared spectrum analysis revealed characteristic bands associated with multiple functional groups. The fiber had monofilaments with diameters around 10 μm and 200 μm, as determined by AFM and SEM images, respectively. Mechanical testing showed the fiber could resist a maximum stress of 355.07 MPa, with an average maximum strain at which breakage occurs of 8.7%. The textile characterization revealed a linear density range of 16.34 to 38.83 tex, with an average value of 25.54 tex and a regain of 13.67%. Thermal analysis showed that the fiber's weight decreased by around 5% due to moisture removal in the range of 40 °C to 100 °C, followed by weight loss due to thermal degradation of hemicellulose and glycosidic linkages of cellulose ranging from 250 to 320 °C. These characteristics suggest that fique fiber can be used in industries such as packaging, construction, composites, and automotive, among others.
文献中现有的许多研究主要集中在纤维的力学特性上,而忽略了其他物理化学和热重分析,这些分析有助于确定其作为工程材料的潜力。本研究对用于潜在工程材料用途的菲克纤维进行了表征。分析了该纤维的化学成分以及物理、热、机械和纺织性能。该纤维具有较高的全纤维素含量以及较低的木质素和果胶含量,这表明其作为各种应用的天然复合材料具有潜力。红外光谱分析揭示了与多个官能团相关的特征谱带。通过原子力显微镜(AFM)和扫描电子显微镜(SEM)图像分别测定,该纤维的单丝直径分别约为10μm和200μm。力学测试表明,该纤维能够承受的最大应力为355.07MPa,断裂时的平均最大应变为8.7%。纺织性能表征显示,线密度范围为16.34至38.83特克斯,平均值为25.54特克斯,回潮率为13.67%。热分析表明,在40℃至100℃范围内,由于水分去除,纤维重量下降约5%,随后在250至320℃范围内,由于半纤维素和纤维素糖苷键的热降解导致重量损失。这些特性表明,菲克纤维可用于包装、建筑、复合材料和汽车等行业及其他领域。