Yang Lu, Liang Xiayu, Ding Yuyang, Li Xinran, Li Xuefeng, Zeng Qingle
Key Laboratory of General Chemistry of the National Ethnic Affairs Commission, Key Laboratory of Pollution Control Chemistry and Environmental Functional Materials for Qinghai-Tibet Plateau of the National Ethnic Affairs Commission, School of Chemistry and Environment, Southwest Minzu University, Chengdu, 610041, People's Republic of China.
College of Materials, Chemistry & Chemical Engineering, Chengdu, 610059, People's Republic of China.
Chem Rec. 2023 Nov;23(11):e202300173. doi: 10.1002/tcr.202300173. Epub 2023 Jul 4.
Enantiomerically enriched five- and six-membered benzo oxygen heterocycles are privileged architectures in functional organic molecules. Over the last several years, many effective methods have been established to access these compounds. However, comprehensive documents cover updated methodologies still in highly demand. In this review, recent transition metal catalyzed transformations lead to chiral five- and six-membered benzo oxygen heterocycles are presented. The mechanism and chirality transfer or control processes are also discussed in details.
对映体富集的五元及六元苯并氧杂环是功能性有机分子中的优势结构。在过去几年中，已经建立了许多有效合成这些化合物的方法。然而，人们仍然迫切需要涵盖最新方法的全面文献。在本综述中，介绍了近期过渡金属催化合成手性五元及六元苯并氧杂环的转化反应。同时，还详细讨论了其反应机理以及手性转移或控制过程。
