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多尺度微花结构超疏水表面的静电空气喷涂法制备。

Multiscale Microflower Structured Superhydrophobic Surface via Electrostatic Air Spray.

机构信息

National Engineering Research Center for High Efficiency Grinding, Hunan University, Changsha 410082, China.

Intelligent Manufacturing College, Hunan Open University, Changsha 410004, China.

出版信息

Langmuir. 2023 Jul 18;39(28):9893-9902. doi: 10.1021/acs.langmuir.3c01124. Epub 2023 Jul 5.

Abstract

Superhydrophobic surfaces with microstructures and multifunctionality have attracted intense research interest. Herein, a multiscale microflower structured surface (MMSS) was successfully fabricated by electrostatic air spray. To systematically study the preparation process, the influences of different electrostatic voltages, solution ratios, soaking time, spray distances, and spray time on surface morphology and hydrophobicity were analyzed. The surface has good superhydrophobic properties with a water contact angle of 162.3°, which allows the surface to be self-cleaning and antifouling. The surface hydrophobicity can be maintained after various mechanical and chemical damages. To overcome the limitation that existing droplet manipulation relies on special materials and surfaces, a new and universal droplet transport method is presented to successfully perform nondestructive droplet manipulations, which relies on external forces and droplet deformation to drive droplets. Therefore, this paper represents a different approach from previous studies of superhydrophobic surfaces and provides a new way to achieve dynamic droplet manipulations. These results indicate that the multifunctional MMSS will be widely used in industrial droplet transportation and self-cleaning applications.

摘要

具有微观结构和多功能的超疏水表面引起了人们的强烈研究兴趣。本文通过静电空气喷涂成功制备了一种多尺度微花结构表面(MMSS)。为了系统地研究制备过程,分析了不同静电电压、溶液比、浸泡时间、喷涂距离和喷涂时间对表面形貌和疏水性的影响。该表面具有良好的超疏水性,水接触角为 162.3°,使表面具有自清洁和防污功能。在经受各种机械和化学损伤后,表面疏水性仍能保持。为了克服现有液滴操作依赖特殊材料和表面的局限性,提出了一种新的通用液滴传输方法,成功地实现了无损液滴操作,该方法依赖于外部力和液滴变形来驱动液滴。因此,本文代表了与超疏水表面的先前研究不同的方法,并提供了实现动态液滴操作的新途径。这些结果表明,多功能 MMSS 将广泛应用于工业液滴输送和自清洁应用中。

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