Verma Neeraj, Michalska-Domańska Marta, Ram Tirath, Kaur Jagjeet, Misra Abhishek Kumar, Dubey Vikas, Dubey Neha, Tiwari Kanchan, Rao M C
Department of Physics, Government Vishwanath Yadav Tamaskar Post Graduate Autonomous College Durg Chhattisgarh India.
Military University of Technology in Warsaw Warsaw Mazovia Poland
RSC Adv. 2023 Jul 5;13(29):20217-20228. doi: 10.1039/d3ra03199c. eCollection 2023 Jun 29.
This research paper reports the synthesis and luminescence study of an Eu activated SrYO phosphor prepared by a modified solid-state reaction method with varying concentrations of Eu ions (0.1-2.5 mol%). X-ray diffraction (XRD) revealed the orthorhombic structure and Fourier transform infrared spectroscopy (FTIR) methods were used to analyse the produced phosphors. Photoluminescence emission and excitation spectra were recorded for varying concentrations of Eu ions, and an optimum concentration of 2.0 mol% was found to produce the highest intensity. Under 254 nm excitation the emission peaks were found to be at 580 nm, 590 nm, 611 nm and 619 nm, corresponding to transitions at D → F, D → F, and D → F respectively. Because of Eu inherent luminosity, these emission peaks indicate radiative transitions between excited states of ions, making them useful for developing white light-emitting phosphors for optoelectronic and flexible display applications. The 1931 CIE (, ) chromaticity coordinates were calculated from the photoluminescence emission spectra and found to be near white light emission, indicating the potential application of the prepared phosphor for light emitting diodes (white component). TL glow curve analysis was also performed for various concentrations of doping ions and UV exposure times, and a single broad peak was observed at 187 °C. Using the computerised glow curve deconvolution (CGCD) method, kinetic parameters were computed.
本研究论文报道了采用改进的固态反应法制备的不同浓度铕离子(0.1 - 2.5 mol%)激活的SrYO磷光体的合成及发光研究。X射线衍射(XRD)揭示了其正交结构,并采用傅里叶变换红外光谱(FTIR)方法对制备的磷光体进行分析。记录了不同浓度铕离子的光致发光发射光谱和激发光谱,发现最佳浓度为2.0 mol%时发光强度最高。在254 nm激发下,发射峰分别位于580 nm、590 nm、611 nm和619 nm,分别对应于(^{5}D_{0}\to^{7}F_{0})、(^{5}D_{0}\to^{7}F_{1})、(^{5}D_{0}\to^{7}F_{2})跃迁。由于铕固有的发光特性,这些发射峰表明离子激发态之间的辐射跃迁,使其可用于开发用于光电和柔性显示应用的白光发射磷光体。根据光致发光发射光谱计算了1931 CIE(x,y)色度坐标,发现接近白光发射,表明所制备的磷光体在发光二极管(白色成分)方面具有潜在应用。还对不同浓度的掺杂离子和紫外线暴露时间进行了热释光发光曲线分析,在187 °C观察到一个单一的宽峰。采用计算机化发光曲线去卷积(CGCD)方法计算了动力学参数。