Nano and Biomaterials Lab, Department of Chemistry, University of Agriculture, Faisalabad, 38040, Pakistan.
Department of Biochemistry, University of Agriculture, Faisalabad, 38040, Pakistan.
Sci Rep. 2023 Jul 9;13(1):11100. doi: 10.1038/s41598-023-37607-x.
Complexation of micronutrients with complexing agents reduce undesirable reactions of fertilizers in soil water system. In the form of complex structure nutrients remain available to plants in the useable form. Nanoform fertilizer enhances the surface area of particles and less amount of fertilizer contact with large area of plant roots which reduce fertilizer cost. Controlling release of fertilizer using polymeric material like sodium alginate makes agriculture practices more efficient and cost effective. Several fertilizers and nutrients are used at a large scale to improve crop yields globally and almost more than half goes to waste. Therefore, there is a dire need to improve plant-available nutrients in soil, using feasible, environmentally friendly technologies. In the present research, complexed micronutrients were successfully encapsulated using a novel technique at nanometric scale. The nutrients were complexed with proline and encapsulated using sodium alginate (polymer). Sweet basil was subjected to seven treatments over three months in a moderately controlled environment (25 °C of temperature and 57% of humidity) to study the effects of synthesized complexed micronutrient nano fertilizers. The structural modifications of the complexed micronutrient nanoforms of fertilizers were examined, through X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). The size of manufactured fertilizers was between 1 and 200 nm. Fourier transform infrared (FTIR) spectroscopy stretching vibration peaks at 1600.9 cm (C=O), 3336 cm (N-H) and at 1090.2 cm (N-H in a twisting and rocking) corresponds to the pyrrolidine ring. Gas chromatography-mass spectrometry was used to analyze the chemical makeup of the essential oil of the basil plants. Essential oil yield of basil plants increased from 0.0035 to 0.1226% after treatments. The findings of the present research show that complexation and encapsulation improve crop quality, essential oil yield, and antioxidant potential of basil.
微量元素与螯合剂形成配合物,减少了肥料在水土体系中的不良反应。以配合物的形式,养分以可利用的形式保持对植物的有效性。纳米肥料增强了颗粒的表面积,与大面积植物根系接触的肥料量减少,从而降低了肥料成本。使用海藻酸钠等聚合材料控制肥料的释放,使农业实践更高效、更具成本效益。全球范围内大量使用多种肥料和养分来提高作物产量,其中近一半被浪费。因此,迫切需要使用可行的、环保的技术来提高土壤中植物可用的养分。在本研究中,成功地在纳米尺度上使用一种新的技术将微量元素包埋在配合物中。将营养物与脯氨酸络合,并使用海藻酸钠(聚合物)包埋。在适度控制的环境(温度为 25°C,湿度为 57%)下,甜罗勒经过三个月的七个处理,研究了合成的配合物纳米肥料中微量元素的效果。通过 X 射线粉末衍射(XRD)和扫描电子显微镜(SEM)检查了肥料的配合物纳米形式的结构修饰。制造的肥料的尺寸在 1 到 200nm 之间。傅里叶变换红外(FTIR)光谱的伸缩振动峰在 1600.9cm(C=O)、3336cm(N-H)和 1090.2cm(扭曲和摇摆中的 N-H)处与吡咯烷环相对应。气相色谱-质谱联用仪用于分析罗勒植物精油的化学成分。处理后,罗勒植物的精油产量从 0.0035%增加到 0.1226%。本研究的结果表明,络合和包埋可以提高罗勒的作物质量、精油产量和抗氧化潜力。