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Ameliorated optical, luminescent and thermo-chemical features of polymer derived PPy-SnO nanocomposite as efficient emissive layer material (EML).

作者信息

Kumar Sanjeev, Bilash Choudhary Ram

机构信息

Nano Structured Composite Materials Laboratory (NCML), Department of Physics, Indian Institute of Technology (Indian School of Mines), Dhanbad, Jharkhand 826004, India.

Nano Structured Composite Materials Laboratory (NCML), Department of Physics, Indian Institute of Technology (Indian School of Mines), Dhanbad, Jharkhand 826004, India.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2023 Dec 5;302:123099. doi: 10.1016/j.saa.2023.123099. Epub 2023 Jul 1.

DOI:10.1016/j.saa.2023.123099
PMID:37429196
Abstract

PPy-SnO (PS) nanocomposite was synthesized with varying doses of SnO through in-situ oxidative polymerization technique. Morphological study was performed through FESEM analysis. Particle size of the 15% PS nanocomposite was estimated in the 13-35 nm range by XRD analysis. Elemental presence and its deconvoluted states in the 15% PS nanocomposite were confirmed by XPS analysis. Optical band gap for optimized 15% PS was calculated ∼1.83 eV. PL intensity increases with increase in the concentration of SnO. Its value was found highest for 15% PS laid in the light blue region (close to white light). CIE color coordinate study of the nanocomposites elucidated that optimized 15% PS could be used as efficient emissive layer material for WLED application. A comparative TGA study of the PPy and 15% PS illustrated that optimized 15% PS nanocomposite proved to have better thermal stability.

摘要

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