NanOLaB, Departamento de Física, Universidade Federal de São Carlos-UFSCar, Rodovia Washington Luiz, Km 235 Monjolinho, CP 676, São Carlos 13565-905, SP, Brazil.
Programa de Pós-Graduação em Engenharia Elétrica (Mestrado), Instituto de Ciência e Tecnologia-Câmpus de Sorocaba, Sorocaba 18087-180, SP, Brazil.
Sensors (Basel). 2023 May 16;23(10):4783. doi: 10.3390/s23104783.
Transparent Conductive Oxides (TCOs) have been widely used as sensors for various hazardous gases. Among the most studied TCOs is SnO, due to tin being an abundant material in nature, and therefore being accessible for moldable-like nanobelts. Sensors based on SnO nanobelts are generally quantified according to the interaction of the atmosphere with its surface, changing its conductance. The present study reports on the fabrication of a nanobelt-based SnO gas sensor, in which electrical contacts to nanobelts are self-assembled, and thus the sensors do not need any expensive and complicated fabrication processes. The nanobelts were grown using the vapor-solid-liquid (VLS) growth mechanism with gold as the catalytic site. The electrical contacts were defined using testing probes, thus the device is considered ready after the growth process. The sensorial characteristics of the devices were tested for the detection of CO and CO gases at temperatures from 25 to 75 °C, with and without palladium nanoparticle deposition in a wide concentration range of 40-1360 ppm. The results showed an improvement in the relative response, response time, and recovery, both with increasing temperature and with surface decoration using Pd nanoparticles. These features make this class of sensors important candidates for CO and CO detection for human health.
透明导电氧化物(TCOs)已广泛用作各种有害气体的传感器。在最受研究的 TCOs 中,SnO 是因为锡在自然界中是一种丰富的材料,因此可以用于可模压的纳米带。基于 SnO 纳米带的传感器通常根据大气与表面的相互作用进行定量,从而改变其电导率。本研究报告了一种基于纳米带的 SnO 气体传感器的制造,其中纳米带的电接触是自组装的,因此传感器不需要任何昂贵且复杂的制造工艺。纳米带是使用金作为催化位点的气-固-液(VLS)生长机制生长的。电接触是使用测试探针定义的,因此在生长过程之后,该器件被认为是准备好的。在 25 至 75°C 的温度下,对器件的传感特性进行了测试,以检测 CO 和 CO 气体,并且在宽浓度范围(40-1360 ppm)内有无钯纳米颗粒沉积。结果表明,相对响应、响应时间和恢复都随着温度的升高以及使用 Pd 纳米颗粒进行表面修饰而得到改善。这些特性使这类传感器成为用于检测 CO 和 CO 以保护人类健康的重要候选者。