Xu Zhuhua, Sun Chuying, Min Siyi, Ye Zilong, Zhao Cong, Li Jingzhou, Liu Zhenghao, Liu Youdi, Li Wen-Di, Tang Man-Chung, Song Qinghua, Fu H Y, Kang Feiyu, Li Jiangyu, Shen Yang, Yu Cunjiang, Wei Guodan
Tsinghua-Berkeley Shenzhen Institute (TBSI), Tsinghua University, Shenzhen, 518055, China.
Tsinghua Shenzhen International Graduate School (SIGS), Tsinghua University, Shenzhen, 518055, China.
Small. 2023 Nov;19(44):e2302072. doi: 10.1002/smll.202302072. Epub 2023 Jul 10.
Spectrally selective narrowband photodetection is critical for near-infrared (NIR) imaging applications, such as for communicationand night-vision utilities. It is a long-standing challenge for detectors based on silicon, to achieve narrowband photodetection without integrating any optical filters. Here, this work demonstrates a NIR nanograting Si/organic (PBDBT-DTBT:BTP-4F) heterojunction photodetector (PD), which for the first time obtains the full-width-at-half-maximum (FWHM) of only 26 nm and fast response of 74 µs at 895 nm. The response peak can be successfully tailored from 895 to 977 nm. The sharp and narrow response NIR peak is inherently attributed to the coherent overlapping between the NIR transmission spectrum of organic layer and diffraction enhanced absorption peak of patterned nanograting Si substrates. The finite difference time domain (FDTD) physics calculation confirms the resonant enhancement peaks, which is well consistent with the experiment results. Meanwhile, the relative characterization indicates that the introduction of the organic film can promote carrier transfer and charge collection, facilitating efficient photocurrent generation. This new device design strategy opens up a new window in developing low-cost sensitive NIR narrowband detection.
光谱选择性窄带光电探测对于近红外(NIR)成像应用至关重要,例如用于通信和夜视设备。对于基于硅的探测器而言,在不集成任何光学滤波器的情况下实现窄带光电探测是一个长期存在的挑战。在此,这项工作展示了一种近红外纳米光栅硅/有机(PBDBT-DTBT:BTP-4F)异质结光电探测器(PD),该探测器首次在895nm处获得了仅26nm的半高宽(FWHM)和74µs的快速响应。响应峰值可以成功地从895nm调整到977nm。尖锐且狭窄的近红外响应峰值本质上归因于有机层的近红外透射光谱与图案化纳米光栅硅衬底的衍射增强吸收峰之间的相干重叠。时域有限差分(FDTD)物理计算证实了共振增强峰,这与实验结果高度一致。同时,相关表征表明有机薄膜的引入可以促进载流子转移和电荷收集,有助于高效光电流的产生。这种新的器件设计策略为开发低成本灵敏近红外窄带探测器开辟了一个新窗口。