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在单一工艺循环中生长的LiNbO:Mg,B晶体的结构、光学性质和物理化学特性：一种用于激光辐射转换的光学材料。

Structure, Optical Properties and Physicochemical Features of LiNbO:Mg,B Crystals Grown in a Single Technological Cycle: An Optical Material for Converting Laser Radiation.

作者信息

Palatnikov Mikhail, Makarova Olga, Kadetova Alexandra, Sidorov Nikolay, Teplyakova Natalya, Biryukova Irina, Tokko Olga

机构信息

Tananaev Institute of Chemistry-Subdivision of the Federal Research Centre, Kola Science Centre of the Russian Academy of Sciences (ICT RAS), 184209 Apatity, Russia.

Solid State Physics Department, Petrozavodsk State University, 185910 Petrozavodsk, Russia.

出版信息

Materials (Basel). 2023 Jun 23;16(13):4541. doi: 10.3390/ma16134541.

DOI:10.3390/ma16134541
PMID:37444856
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10342982/
Abstract

Two series of LiNbO:Mg:B crystals have been grown and studied. Two doping methods-have been used. The crystals-have been co-doped with Mg and a non-metallic dopant, B. The physicochemical features of the growth-have been considered for LiNbO:Mg:B crystals obtained from a boron-doped melt. The charge-has been prepared using different technologies: homogeneous (HG) and solid-phase (SP) doping. The same two methods have been used to grow single-doped LiNbO:Mg crystals. A control near-stoichiometric (NSLN) crystal-has been grown via the HTTSSG (high-temperature top-seeded solution growth) method from a congruent melt (Li/Nb ≈ 0.946) with 5.5 wt% KO. The characteristics of the LiNbO:Mg:B crystals-have been compared with those of the LiNbO:Mg and NSLN crystals. Physicochemical and structural reasons have been established for the differences in the distribution coefficients of magnesium (K) during the growth of the HG- and SP-doped LiNbO:B:Mg and LiNbO:Mg crystals. The optical characteristics of the LiNbO:B:Mg crystals-have been studied via optical spectroscopy, laser conoscopy and photoinduced light scattering (PILS). The influence of boron on the microstructure, compositional and optical uniformities and optical damage resistance of the LiNbO:Mg:B crystals-has been estimated. Optimal technological approaches to growing optically uniform LiNbO:B:Mg crystals have been determined. LiNbO:Mg:B crystals have been shown to have a significant advantage over the commercially used LiNbO:Mg crystals since large LiNbO:Mg:B crystals can be grown without stripes. Such stripes usually appear perpendicular to the growth axis. In addition, the photorefractive effect is suppressed in LiNbO:Mg:B crystals at lower magnesium concentrations ([Mg] ≈ 2.5 mol%) than in LiNbO:Mg ([Mg] ≈ 5.5 mol%).

摘要

已经生长并研究了两系列的LiNbO:Mg:B晶体。使用了两种掺杂方法。晶体被镁和一种非金属掺杂剂硼共掺杂。对于从硼掺杂熔体中获得的LiNbO:Mg:B晶体，考虑了其生长的物理化学特性。电荷使用不同技术制备：均匀（HG）掺杂和固相（SP）掺杂。相同的两种方法用于生长单掺杂的LiNbO:Mg晶体。通过高温顶部籽晶溶液生长（HTTSSG）方法，从含有5.5 wt% KO的同成分熔体（Li/Nb≈0.946）中生长出一块对照近化学计量比（NSLN）晶体。将LiNbO:Mg:B晶体的特性与LiNbO:Mg和NSLN晶体的特性进行了比较。确定了在HG掺杂和SP掺杂的LiNbO:B:Mg和LiNbO:Mg晶体生长过程中镁分布系数（K）差异的物理化学和结构原因。通过光谱学、激光锥光法和光致光散射（PILS）研究了LiNbO:B:Mg晶体的光学特性。评估了硼对LiNbO:Mg:B晶体微观结构、成分和光学均匀性以及抗光损伤性能的影响。确定了生长光学均匀的LiNbO:B:Mg晶体的最佳工艺方法。已表明LiNbO:Mg:B晶体相对于商业使用的LiNbO:Mg晶体具有显著优势，因为可以生长出无条纹的大尺寸LiNbO:Mg:B晶体。这种条纹通常垂直于生长轴出现。此外，在较低镁浓度（[Mg]≈2.5 mol%）下，LiNbO:Mg:B晶体中的光折变效应比LiNbO:Mg（[Mg]≈5.5 mol%）中受到抑制。

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