Zhang Hailong, Li Shiyu, Zheng Hongpeng, Han Zhongzhi, Lin Bing, Wang Yingying, Guo Xiaojun, Zhou Taigang, Zhang Haibing, Wu Jianjun, Zhang Hui, Tang Junlei
School of Chemistry and Chemical Engineering & Institute for Carbon Neutrality, Southwest Petroleum University, Chengdu 610500, China.
CNPC Engineering Technology Research Company Limited, Tianjin 300451, China.
Molecules. 2023 Jun 28;28(13):5044. doi: 10.3390/molecules28135044.
Hydrogen sulfide (HS) is widely found in oil and natural gas wells and industrial wastewater tanks. Owing to its high toxicity, the monitoring and detection of HS in the air is essential. However, recent techniques for the quantitative detection of HS gas suffer from limitations such as high cost, complicated operation, and insufficient sensitivity, preventing their practical application in industry. Thus, we have developed a portable test paper for real-time and inexpensive monitoring of HS gas by color changes. The test paper had a significantly low HS detection limit of 200 ppb, which is considered safe for humans. Moreover, the color of the test paper did not change noticeably when exposed to CO, N, O, and air environments, indicating that the test paper is selective for HS gas and can be stored for a long time. In addition, we fitted a color difference linear model between the color difference values (Δ) and the concentrations of HS gas. The establishment of the linear model substantiates that the test paper can provide accurate intensity information when detecting HS gas leakage.
硫化氢(HS)广泛存在于油井、天然气井和工业废水池中。由于其高毒性,对空气中硫化氢的监测和检测至关重要。然而,最近用于定量检测硫化氢气体的技术存在成本高、操作复杂和灵敏度不足等局限性,阻碍了它们在工业中的实际应用。因此,我们开发了一种便携式试纸,通过颜色变化对硫化氢气体进行实时、低成本监测。该试纸的硫化氢检测限低至200 ppb,对人体而言被认为是安全的。此外,当试纸暴露于一氧化碳、氮气、氧气和空气环境中时,其颜色没有明显变化,这表明该试纸对硫化氢气体具有选择性,并且可以长期保存。此外,我们拟合了色差(Δ)值与硫化氢气体浓度之间的色差线性模型。线性模型的建立证实了该试纸在检测硫化氢气体泄漏时能够提供准确的强度信息。