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基于黄原胶生物聚合物的土壤处理对高岭土黏土结构和织构的XRD分析

Xanthan biopolymer-based soil treatment effect on kaolinite clay fabric and structure using XRD analysis.

作者信息

Kwon Yeong-Man, Chang Ilhan, Cho Gye-Chun

机构信息

Department of Civil and Environmental Engineering, Northwestern University, Evanston, IL, 60208, USA.

Department of Civil Systems Engineering, Ajou University, Suwon, 16499, Republic of Korea.

出版信息

Sci Rep. 2023 Jul 19;13(1):11666. doi: 10.1038/s41598-023-38844-w.

Abstract

In this study, we evaluated the impact of xanthan gum biopolymer (XG) on kaolinite fabrics using X-ray diffraction (XRD) and the ensuing changes in the compaction behavior and shear resistance of kaolinite soils. The XRD peak analysis revealed that XG changed kaolinite fabrics into face-to-face associations. Moreover, environmental scanning electron microscopy showed the formation of XG-bridges between kaolinite particles, resulting in the change in fabrics and subsequently improving the resistance of kaolinite to external forces. Consequently, as XG content increased, the maximum dry density decreased, and the undrained shear strength increased. The viscous XG hydrogels produced a higher optimal moisture content and increased resistance to shear force. This study showed that XG affects the mechanical properties of kaolinite through changing kaolinite fabrics (up to 0.5% of the XG-to-kaolinite mass ratio) and absorbing pore-fluids (excess XG over 0.5% of the XG-to-kaolinite mass ratio).

摘要

在本研究中,我们使用X射线衍射(XRD)评估了黄原胶生物聚合物(XG)对高岭土织物的影响,以及高岭土土壤压实行为和抗剪强度随之发生的变化。XRD峰分析表明,XG将高岭土织物转变为面对面缔合。此外,环境扫描电子显微镜显示在高岭土颗粒之间形成了XG桥,导致织物发生变化,进而提高了高岭土对外力的抵抗力。因此,随着XG含量的增加,最大干密度降低,不排水抗剪强度增加。粘性XG水凝胶产生了更高的最佳含水量并增加了抗剪切力。本研究表明,XG通过改变高岭土织物(XG与高岭土质量比高达0.5%)和吸收孔隙流体(XG超过XG与高岭土质量比的0.5%)来影响高岭土的力学性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/987b/10356783/76d6bbe0d8cf/41598_2023_38844_Fig1_HTML.jpg

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