Bifunctional CuS/Cl-terminated greener MXene electrocatalyst for efficient hydrogen production by water splitting.

Metal sulfides and 2D materials are the propitious candidates for numerous electrochemical applications, due to their superior conductivity and ample active sites. Herein, CuS nanoparticles were fabricated on 2D greener HF-free Cl-terminated MXene (TiCCl) sheets by the hydrothermal process as a proficient electrocatalyst for the hydrogen evolution reaction (HER) and overall water splitting. CuS/TiCCl showed an overpotential of 163 mV and a Tafel slope of 77 mV dec at 10 mA cm for the HER. In the case of the OER, CuS/TiCCl exhibited an overpotential of 334 mV at 50 mA cm and a Tafel slope of 42 mV dec. Moreover, the assembled CuS/TiCCl||CuS/TiCCl electrolyzer delivered current density of 20 mA cm at 1.87 V for overall water splitting. The CuS/TiCCl electrocatalyst showed excellent stability to retain 96% of its initial value for about 48 hours at 100 mA cm current density. The synthesis of CuS/TiCCl enriches the applications of MXene/metal sulfides in efficient bifunctional electrocatalysis for alkaline water splitting.