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通过单壁碳纳米管薄膜涂层提高聚对苯二甲酸乙二酯的导电性和强度

Enhancing the Electrical Conductivity and Strength of PET by Single-Wall Carbon Nanotube Film Coating.

作者信息

Ding Wu-Tong, Jiao Xin-Yu, Zhao Yi-Ming, Sun Xin-Yang, Chen Chao, Wu An-Ping, Ding Yu-Tian, Hou Peng-Xiang, Liu Chang

机构信息

Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China.

School of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China.

出版信息

ACS Appl Mater Interfaces. 2023 Aug 9;15(31):37802-37809. doi: 10.1021/acsami.3c06671. Epub 2023 Jul 28.

Abstract

Single-wall carbon nanotubes (SWCNTs) with excellent physicochemical properties are considered a promising candidate for the electrical and mechanical reinforcements of polymers. However, the poor dispersion of SWCNTs in plastics seriously limits their application and their achieved performance enhancement. Here, we coat a freestanding, highly conductive SWCNT film onto the surface of a polyethylene terephthalate (PET) film by a hot-pressing method. Due to the uniform SWCNT network structure and strong interfacial interaction, the SWCNT/PET hybrid film showed notably enhanced electrical and mechanical properties even though with a very low SWCNT weight fraction of 0.066%. The surface square resistance of the SWCNT/PET film decreased to 120-140 Ω/□ from 10 Ω. In addition, Young's modulus and tensile strength of the SWCNT/PET film reached 4.6 GPa and 148 MPa, which are 31.3 and 24.4%, respectively, higher than the pure PET film. The SWCNT/PET film shows excellent mechanical durability and thermal stability, demonstrating its potential use as an antistatic material.

摘要

具有优异物理化学性质的单壁碳纳米管(SWCNTs)被认为是聚合物电气和机械增强的有前途的候选材料。然而,SWCNTs在塑料中的分散性差严重限制了它们的应用及其所实现的性能提升。在此,我们通过热压法将独立的、高导电性的SWCNT薄膜涂覆在聚对苯二甲酸乙二酯(PET)薄膜表面。由于均匀的SWCNT网络结构和强界面相互作用,即使SWCNT重量分数非常低,仅为0.066%,SWCNT/PET混合薄膜仍表现出显著增强的电气和机械性能。SWCNT/PET薄膜的表面方阻从10Ω降至120 - 140Ω/□。此外,SWCNT/PET薄膜的杨氏模量和拉伸强度分别达到4.6 GPa和148 MPa,比纯PET薄膜分别高出31.3%和24.4%。SWCNT/PET薄膜表现出优异的机械耐久性和热稳定性,证明了其作为抗静电材料的潜在用途。

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