Menshutina Natalia, Abramov Andrey, Okisheva Maria, Tsygankov Pavel
Department of Chemical and Pharmaceutical Engineering, Mendeleev University of Chemical Technology of Russia, Miusskaya pl. 9, 125047 Moscow, Russia.
Gels. 2023 Jul 12;9(7):566. doi: 10.3390/gels9070566.
Direct ink writing (DIW) requires careful selection of ink composition with specific rheological properties, and it has limitations, such as the inability to create overhanging parts or branched geometries. This study presents an investigation into enhancing the 3D printing process through the use of a heterophase system, aiming to overcome these limitations. A modification was carried out in the 3D printer construction, involving adjustments to the structural elements responsible for the extrusion device's movement. Additionally, a method for obtaining a heterophase system based on gelatin microparticles was developed to enable the 3D printing process with the upgraded printer. The structure and rheological properties of the heterophase system, varying in gelatin concentration, were thoroughly examined. The material's viscosity ranged from 5.4 to 32.8 kPa·s, exhibiting thixotropic properties, pseudoplastic behavior, and long-term stability at 20 °C. The developed 3D printing technology was successfully implemented using a heterophase system based on different gelatin concentrations. The highest product quality was achieved with a heterophase system consisting of 4.5 wt.% gelatin, which exhibited a viscosity of 22.4 kPa·s, enabling the production of products without spreading or compromising geometrical integrity.
直接墨水书写(DIW)需要仔细选择具有特定流变特性的墨水成分,并且它存在局限性,例如无法创建悬垂部分或分支几何形状。本研究对通过使用异相系统来改进3D打印过程进行了调查,旨在克服这些局限性。对3D打印机的构造进行了修改,包括对负责挤出装置运动的结构元件进行调整。此外,还开发了一种基于明胶微粒获得异相系统的方法,以便能够使用升级后的打印机进行3D打印过程。对不同明胶浓度的异相系统的结构和流变特性进行了全面研究。该材料的粘度范围为5.4至32.8 kPa·s,在20°C下表现出触变性、假塑性行为和长期稳定性。基于不同明胶浓度的异相系统成功实现了所开发的3D打印技术。由4.5 wt.%明胶组成的异相系统实现了最高的产品质量,其粘度为22.4 kPa·s,能够生产出不会扩散或损害几何完整性的产品。