Berning Torsten, Bessarabov Dmitri
Department of Energy, Aalborg University, 9220 Aalborg, Denmark.
Hydrogen South Africa Infrastructure (HySA), Faculty of Engineering, North-West University, Potchefstroom 2520, South Africa.
Membranes (Basel). 2023 Jun 21;13(7):614. doi: 10.3390/membranes13070614.
We are proposing a conceptual membrane electrode assembly (MEA) of a proton exchange membrane water electrolyzer that includes a layer of graphene oxide (GO) at the cathode side. This GO layer primarily reinforces the MEA to allow operation at a higher pressure difference between the cathode and anode side. Additional benefits would be that a perfect GO layer would prevent both water and hydrogen crossover and thus would allow for pure, dry hydrogen escaping directly from the electrolyzer without losses due to hydrogen crossover, thus eliminating the need for hydrogen clean-up steps. The mechanical strength of graphene will also allow for a thinner polymer electrolyte membrane and could thus save cost. Finally, the effect of electro-osmotic drag on the water content in such an MEA is discussed, and it is argued that it could lead to an oversaturated membrane, which is highly desirable.
我们正在提出一种质子交换膜水电解槽的概念性膜电极组件(MEA),该组件在阴极侧包含一层氧化石墨烯(GO)。该GO层主要增强MEA,以允许在阴极和阳极侧之间更高的压差下运行。额外的好处是,完美的GO层将防止水和氢气渗透,从而允许纯净、干燥的氢气直接从电解槽逸出,而不会因氢气渗透而损失,从而无需氢气净化步骤。石墨烯的机械强度还将允许使用更薄的聚合物电解质膜,从而可以节省成本。最后,讨论了电渗拖拽对这种MEA中水含量的影响,并认为这可能导致膜过度饱和,这是非常理想的。