Effect of Current Density on the Corrosion Resistance and Photocatalytic Properties of Cu-Ni-ZnNiCuO Nanocomposite Coatings.

2 at.% Cu + 2 at.% Ni were co-doped in ZnO nanoparticles by a simple hydrothermal method, and then the modified nanoparticles were compounded into Cu-Ni alloy coatings using an electroplating technique. The effects of the current density (15-45 mA/cm) on the phase structure, surface morphology, thickness, microhardness, corrosion resistance, and photocatalytic properties of the coatings were investigated. The results show that the Cu-Ni-ZnNiCuO nanocomposite coatings had the highest compactness and the best overall performance at a current density of 35 mA/cm. At this point, the co-deposition rate reached its maximum, resulting in the deposition of more ZnNiCuO nanoparticles in the coating. More nanoparticles were dispersed in the coating with a better particle strengthening effect, which resulted in a minimum crystallite size of 15.21 nm and a maximum microhardness of 558 HV. Moreover, the surface structure of the coatings became finer and denser. Therefore, the corrosion resistance was significantly improved with a corrosion current density of 2.21 × 10 mA/cm, and the charge transfer resistance was up to 20.98 kΩ·cm. The maximum decolorization rate of the rhodamine B solution was 24.08% under ultraviolet light irradiation for 5 h. The improvement in the comprehensive performance was mainly attributed to the greater concentration of ZnNiCuO nanoparticles in the coating, which played the role of the particle-reinforced phase and reduced the microstructure defects.