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碳酸钾促进的α,β-不饱和羰基化合物与萘酚的氧-迈克尔加成/环化反应:萘并吡喃的合成

KCO-Promoted oxy-Michael Addition/Cyclization of ,-Unsaturated Carbonyl Compounds with Naphthols: Synthesis of Naphthopyrans.

作者信息

Li Shan-Shan, Zhao Li-Li, Pan Min, Feng Na, Peng Jin-Bao, Ma Ai-Jun

机构信息

School of Biotechnology and Health Sciences, Wuyi University, Jiangmen 529020, China.

出版信息

Molecules. 2023 Jul 19;28(14):5502. doi: 10.3390/molecules28145502.

Abstract

A potassium carbonate promoted tandem oxy-Michael addition/cyclization of ,-unsaturated carbonyl compounds with naphthol derivatives for the synthesis of 2-substituted naphthopyrans was developed. Using the readily available, inexpensive potassium carbonate as the promoter, a range of different substituted naphthopyrans were prepared.

摘要

开发了一种碳酸钾促进的α,β-不饱和羰基化合物与萘酚衍生物的串联氧-迈克尔加成/环化反应,用于合成2-取代萘并吡喃。使用易于获得的廉价碳酸钾作为促进剂,制备了一系列不同取代的萘并吡喃。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/70ee/10385152/b02751c2dc5c/molecules-28-05502-g001.jpg

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