Su Qian, Zuo Cheng, Liu Meifang, Tai Xishi
College of Chemistry & Chemical and Environmental Engineering, Weifang University, Weifang 261061, China.
Molecules. 2023 Jul 22;28(14):5576. doi: 10.3390/molecules28145576.
Photocatalysis technology has the advantages of being green, clean, and environmentally friendly, and has been widely used in CO reduction, hydrolytic hydrogen production, and the degradation of pollutants in water. CuO has the advantages of abundant reserves, a low cost, and environmental friendliness. Based on the narrow bandgap and strong visible light absorption ability of CuO, CuO-based composite materials show infinite development potential in photocatalysis. However, in practical large-scale applications, CuO-based composites still pose some urgent problems that need to be solved, such as the high composite rate of photogenerated carriers, and poor photocatalytic activity. This paper introduces a series of CuO-based composites, based on recent reports, including pure CuO and CuO hybrid materials. The modification strategies of photocatalysts, critical physical and chemical parameters of photocatalytic reactions, and the mechanism for the synergistic improvement of photocatalytic performance are investigated and explored. In addition, the application and photocatalytic performance of CuO-based photocatalysts in CO photoreduction, hydrogen production, and water pollution treatment are discussed and evaluated. Finally, the current challenges and development prospects are pointed out, to provide guidance in applying CuO-based catalysts in renewable energy utilization and environmental protection.
光催化技术具有绿色、清洁、环保等优点,已广泛应用于CO还原、水解制氢及水中污染物降解等领域。CuO具有储量丰富、成本低、环境友好等优势。基于CuO的窄带隙和较强的可见光吸收能力,CuO基复合材料在光催化方面展现出无限的发展潜力。然而,在实际大规模应用中,CuO基复合材料仍存在一些亟待解决的问题,如光生载流子复合率高、光催化活性差等。本文基于近期报道介绍了一系列CuO基复合材料,包括纯CuO及CuO杂化材料。研究并探讨了光催化剂的改性策略、光催化反应的关键物理化学参数以及光催化性能协同提升的机理。此外,还对CuO基光催化剂在CO光还原、制氢及水污染处理中的应用及光催化性能进行了讨论和评估。最后指出了当前面临的挑战和发展前景,为CuO基催化剂在可再生能源利用和环境保护中的应用提供指导。