Zhang Yong-Hui, Liu Ming-Ming, Chen Jun-Li, Fang Shao-Ming, Zhou Pan-Pan
College of Materials and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, P. R. China.
Dalton Trans. 2021 Mar 28;50(12):4091-4111. doi: 10.1039/d0dt04434b. Epub 2021 Mar 12.
CuO-based composites for photocatalysis have been extensively explored owing to their promising application in solving environmental and energy problems. At present, the research on photocatalysis is focused on improving the photocatalytic performance of materials. It has been reported that adjusting the morphology and size of CuO can effectively improve its photocatalytic property. However, photocorrosion is still an inevitable problem, which hinders the application of CuO in photocatalysis. The strategies of constructing heterogeneous nanostructures and ion doping can significantly improve the light stability, light absorption capacity and separation efficiency of electron-hole pairs. CuO-based composites exhibit superior performances in degrading organic matter, producing hydrogen, reducing CO and sterilization. Therefore, the construction of multi-materials will be one of the future directions in their photocatalytic application. This review summarizes the recent strategies for enhancing the photocatalytic activity of CuO by analyzing different CuO-based photocatalysts, and the charge transfer pathway is further discussed in detail. Finally, several opportunities and challenges in the field of photocatalysis are illustrated.
由于基于CuO的光催化复合材料在解决环境和能源问题方面具有广阔的应用前景,因此受到了广泛的研究。目前,光催化研究主要集中在提高材料的光催化性能上。据报道,调整CuO的形貌和尺寸可以有效提高其光催化性能。然而,光腐蚀仍然是一个不可避免的问题,这阻碍了CuO在光催化中的应用。构建异质纳米结构和离子掺杂的策略可以显著提高光稳定性、光吸收能力和电子-空穴对的分离效率。基于CuO的复合材料在降解有机物、产氢、还原CO和杀菌方面表现出优异的性能。因此,构建多材料体系将是其光催化应用的未来发展方向之一。本文综述了通过分析不同的CuO基光催化剂来提高CuO光催化活性的最新策略,并详细讨论了电荷转移途径。最后,阐述了光催化领域的若干机遇和挑战。