Department of Chemistry, D.B.S. (PG) College Dehradun, Uttarakhand, India.
Crit Rev Anal Chem. 2024;54(8):3269-3312. doi: 10.1080/10408347.2023.2238066. Epub 2023 Jul 30.
Mercury, a highly toxic heavy metal, poses significant environmental and health risks, necessitating the development of effective and responsive techniques for its detection. Organic chromophores, particularly small molecules, have emerged as promising materials for sensing Hg ions due to their high selectivity, sensitivity, and ease of synthesis. In this review article, we provide a systematic overview of recent advancements in the field of fluorescent chemosensors for Hg ions detection, including rhodamine derivatives, Schiff bases, coumarin derivatives, naphthalene derivatives, BODIPY, BOPHY, naphthalimide, pyrene, dicyanoisophorone, bromophenol, benzothiazole flavonol, carbonitrile, pyrazole, quinoline, resorufin, hemicyanine, monothiosquaraine, cyanine, pyrimidine, peptide, and quantum/carbon dots probes. We discuss their detection capabilities, sensing mechanisms, limits of detection, as well as the strategies and approaches employed in their design. By focusing on recent studies conducted between 2022 and 2023, this review article offers valuable insights into the performance and advancements in the field of fluorescent chemosensors for Hg ions detection.
汞是一种毒性很强的重金属,对环境和健康构成重大风险,因此需要开发有效和响应迅速的技术来检测它。有机发色团,特别是小分子,由于其高选择性、灵敏度和易于合成,已成为检测 Hg 离子的有前途的材料。在这篇综述文章中,我们系统地概述了近年来用于检测 Hg 离子的荧光化学传感器领域的最新进展,包括罗丹明衍生物、席夫碱、香豆素衍生物、萘衍生物、BODIPY、BOPHY、萘酰亚胺、芘、二氰基异佛尔酮、溴苯酚、苯并噻唑黄酮醇、腈、吡唑、喹啉、若丹明、半花青、单硫代方酸菁、氰基、嘧啶、肽和量子/碳点探针。我们讨论了它们的检测能力、传感机制、检测限,以及在设计中采用的策略和方法。通过重点关注 2022 年至 2023 年期间进行的最新研究,本文为荧光化学传感器检测 Hg 离子的性能和进展提供了有价值的见解。