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冷喷涂制备的金刚石增强铜和铝金属基复合材料的力学性能与疲劳性能

Mechanical and Fatigue Properties of Diamond-Reinforced Cu and Al Metal Matrix Composites Prepared by Cold Spray.

作者信息

Kovarik O, Cizek J, Yin S, Lupoi R, Janovska M, Cech J, Capek J, Siegl J, Chraska T

机构信息

Faculty of Nuclear Sciences and Physical Engineering, Czech Technical University in Prague, Prague, Czech Republic.

Institute of Plasma Physics of the Czech Academy of Sciences, Prague, Czech Republic.

出版信息

J Therm Spray Technol. 2022;31(1-2):217-233. doi: 10.1007/s11666-022-01321-3. Epub 2022 Jan 26.

Abstract

Diamond-reinforced metal matrix composites (DMMC) prepared by cold spray are emerging materials simultaneously featuring outstanding thermal conductivity and wear resistance. In our paper, their mechanical and fatigue properties relevant to perspective engineering applications were investigated using miniature bending specimens. Two different diamond mass concentrations (20 and 50%) embedded in two metal matrices (Al-lighter than diamond, Cu-heavier than diamond) were compared with the respective cold-sprayed pure metals, as well as bulk Al and Cu references. The pure Al, Cu coatings showed properties typical for cold spray deposits, i.e., decreased elastic moduli (50 GPa for Al, 80 GPa for Cu), limited ductility (< 1 × 10) and low fracture toughness (3.8 MPa·m for Al, 5.6 MPa·m for Cu) when compared to the bulks. Significantly improved properties (strain at fracture, ultimate strength, fatigue crack growth resistance, fracture toughness) were then observed for the produced DMMC. The improvement can be explained by a combination of two factors: changes in the properties of the metallic matrix triggered by the reinforcement particles peening effect and stress redistribution due to the particles presence.

摘要

通过冷喷涂制备的金刚石增强金属基复合材料(DMMC)是一种新型材料,同时具有出色的热导率和耐磨性。在我们的论文中,使用微型弯曲试样研究了它们与潜在工程应用相关的力学和疲劳性能。将两种不同质量浓度(20%和50%)的金刚石嵌入两种金属基体(比金刚石轻的Al和比金刚石重的Cu)中,并与各自的冷喷涂纯金属以及块状Al和Cu参考材料进行比较。与块状材料相比,纯Al、Cu涂层表现出冷喷涂沉积物典型的性能,即弹性模量降低(Al为50 GPa,Cu为80 GPa)、延展性有限(< 1×10)以及断裂韧性较低(Al为3.8 MPa·m,Cu为5.6 MPa·m)。然后观察到所制备的DMMC的性能有显著改善(断裂应变、极限强度、抗疲劳裂纹扩展能力、断裂韧性)。这种改善可以由两个因素的组合来解释:增强颗粒的喷丸效应引发的金属基体性能变化以及由于颗粒存在导致的应力重新分布。

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