Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, National University of Defense Technology, Changsha, 410073, China.
Suzhou Institute of Nanotech and Nanobionics, Chinese Academy of Sciences, Suzhou, 215123, China.
Adv Mater. 2023 Nov;35(47):e2302973. doi: 10.1002/adma.202302973. Epub 2023 Oct 22.
The unmet spectral mimicry of foliar green in camouflage materials is hampered by the lack of colorants with similar spectral properties to chlorophyll, resulting in substantial risks of exposure from hyperspectral target detection. By drawing inspiration from leaf chromogenesis, a microcapsule colorant with a chloroplast-like structure and chlorophyll-like absorption is developed, and a generic bilayer coating is designed to provide high spectral similarity to leaves with different growth stages, seasons, and species. Specifically, the microcapsule colorant preserves the monomeric absorption of the internal phthalocyanine and features the manufacturability of conventional pigments, such as amenability to painting and patterning, and compatibility to different substrates. The pigmented artificial leaves successfully deceive the hyperspectral classification algorithm in a foliar background, and outperforming the state-of-art spectral simulation materials. This coloration strategy expands the knowledge base of the spectral fine tuning of composite colorants, which are essential for their application in spectral-resolved optical materials.
伪装材料中叶片绿色的未满足的光谱模拟受到缺乏与叶绿素具有相似光谱特性的着色剂的阻碍,这导致了来自超光谱目标探测的暴露的实质性风险。通过从叶色发生中汲取灵感,开发了一种具有类叶绿体结构和叶绿素样吸收的微胶囊着色剂,并设计了通用的双层涂层,以提供与不同生长阶段、季节和物种的叶片具有高度光谱相似性。具体来说,微胶囊着色剂保留了内部酞菁的单体吸收,并具有传统颜料的可制造性,如可涂漆和图案化,以及与不同基底的兼容性。着色的人工叶子成功地欺骗了叶片背景中的超光谱分类算法,并优于最先进的光谱模拟材料。这种着色策略扩展了复合着色剂光谱微调的知识库,这对于它们在光谱分辨光学材料中的应用至关重要。