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由二氧化碳和氨直接合成尿素。

Direct synthesis of urea from carbon dioxide and ammonia.

作者信息

Ding Jie, Ye Runping, Fu Yanghe, He Yiming, Wu Ye, Zhang Yulong, Zhong Qin, Kung Harold H, Fan Maohong

机构信息

School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing, Jiangsu, 210094, P. R. China.

College of Engineering and Applied Sciences, and School of Energy Resources, University of Wyoming, Laramie, WY, 82071, USA.

出版信息

Nat Commun. 2023 Jul 31;14(1):4586. doi: 10.1038/s41467-023-40351-5.

DOI:10.1038/s41467-023-40351-5
PMID:37524739
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10390537/
Abstract

Urea is an essential fertilizer needed to meet the global demand for food. Currently, its production rate by reaction of carbon dioxide with ammonia is slow and the energy demand is high. Here we discuss strategies to overcome these challenges.

摘要

尿素是满足全球粮食需求所需的一种重要肥料。目前,通过二氧化碳与氨反应生产尿素的速率较慢,且能源需求较高。在此,我们讨论克服这些挑战的策略。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f465/10390537/acb275b3a457/41467_2023_40351_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f465/10390537/91f78ba2fd8b/41467_2023_40351_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f465/10390537/acb275b3a457/41467_2023_40351_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f465/10390537/91f78ba2fd8b/41467_2023_40351_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f465/10390537/acb275b3a457/41467_2023_40351_Fig2_HTML.jpg

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Commun Chem. 2021 May 14;4(1):66. doi: 10.1038/s42004-021-00505-2.
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Conversion of Recovered Ammonia and Carbon Dioxide into Urea in the Presence of Catalytically Active Copper Species in Nanospaces of Porous Silica Hollow Spheres.在多孔硅质空心球纳米空间中催化活性铜物种的存在下,将回收的氨和二氧化碳转化为尿素。
ACS Appl Mater Interfaces. 2023 Feb 1;15(4):5109-5117. doi: 10.1021/acsami.2c17560. Epub 2023 Jan 20.
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Chemical looping based ammonia production-A promising pathway for production of the noncarbon fuel.
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