Heinl Sebastian, Peresypkina Eugenia, Kremer Werner, Scheer Manfred
Institute of Inorganic Chemistry, University of Regensburg, Universitätsstraße 31, Regensburg 93040, Germany.
Institute of Biophysics and Physical Biochemistry, University of Regensburg, Universitätsstraße 31, Regensburg 93040, Germany.
Chem Commun (Camb). 2023 Aug 22;59(68):10263-10266. doi: 10.1039/d3cc03244b.
Besides inherent fullerene-like hollow spheres, the metallasupramolecular chemistry of pentaphosphaferrocenes and CuBr afforded a conceptually new product, a compact 3.2 nm sized supramolecule [{1d}(CuBr)(CHCN)] formed by six largest pentaphosphaferrocene units [CpFe(η-P)] (1d: Cp = η-C(4-BuCH)) so far and a framework of 32 copper and 32 bromide ions.
除了固有的类富勒烯空心球外，五磷杂二茂铁与溴化铜的金属超分子化学还提供了一种概念上全新的产物，即一种由六个迄今最大的五磷杂二茂铁单元[CpFe(η-P)]（1d：Cp = η-C(4-BuCH)）形成的紧凑的3.2纳米大小的超分子[{1d}(CuBr)(CHCN)]，以及一个由32个铜离子和32个溴离子组成的框架。
