Liu Yu-Hang, Wu Yi-Fan, Feng Li-Juan, Zhao Rui-Rui, Wang Shan-Xiao, Zhang Ming-Ming, Wang Dan-Yang, Kong Xiang-Wen, Lei Xiao-Wu
School of Chemistry, Chemical Engineer and Materials, Jining University, Qufu, Shandong, 273155, P. R. China.
School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, Shandong, 273165, P. R. China.
Chem Commun (Camb). 2023 Aug 22;59(68):10267-10270. doi: 10.1039/d3cc02093b.
Herein, we for the first time report a reversible conversion between green-emissive [DMPZ]MnCl and red-emissive DMPZ(MnCl)(HO) (DMPZ = 1,4-dimethylpiperazine) using kinetic and thermodynamic controlling strategies. Significantly, the synchronous structural and emission transformations in single-component organic manganese halides with adjustable emission colors are highlighted.
在此，我们首次报道了使用动力学和热力学控制策略，在绿色发光的[DMPZ]MnCl和红色发光的DMPZ(MnCl)(H₂O)（DMPZ = 1,4 - 二甲基哌嗪）之间实现可逆转换。值得注意的是，突出了具有可调发射颜色的单组分有机锰卤化物中的同步结构和发射转变。
