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台湾市售含油包装食品中缩水甘油酯和 3-单氯丙二醇酯的人群暴露初步评估。

Preliminary assessments of population exposure to glycidyl esters and 3-monochloropropane-1,2-diol esters from miscellaneous oil-containing packaged foods in Taiwan.

机构信息

Master Program in Food Safety, College of Nutrition, Taipei Medical University, Taipei, Taiwan.

School of Food Safety, College of Nutrition, Taipei Medical University, Taipei, Taiwan.

出版信息

Food Chem. 2024 Jan 1;430:137055. doi: 10.1016/j.foodchem.2023.137055. Epub 2023 Jul 31.

Abstract

Glycidyl esters (GEs) and 3-monochloropropane-1,2-diol esters (3-MCPDEs) are carcinogenic contaminants found in refined oils. This study aimed to determine levels of GEs and 3-MCPDEs in packaged foodstuffs, and estimate daily exposure levels using food consumption data. The analysis involved Soxtec extraction and gas chromatography-mass spectrometry, and the recovery of spiked GEs and 3-MCPDEs was within the range of 80%∼110%. Results showed that GEs and 3-MCPDEs were almost ubiquitous in food products (95%), with the highest concentrations found in processed fats, followed by cookies and spreads. Food products containing palm-derived oils had significantly higher levels of contaminants (p < 0.05), with up to 58.1% of palm oil-containing foodstuffs exceeding the upper limits of either GEs or 3-MCPDEs set by the European Union. Cookies and instant noodles were identified as the main sources of exposure to GEs and 3-MCPDEs, with potential daily intake levels exceeding the tolerable daily intakes in children aged 0 ∼ 12 years.

摘要

缩水甘油酯(GEs)和 3-单氯丙二醇酯(3-MCPDEs)是精炼油中发现的致癌污染物。本研究旨在测定包装食品中 GEs 和 3-MCPDEs 的含量,并利用食物消费数据评估每日摄入量。分析采用 Soxtec 提取和气相色谱-质谱法,GEs 和 3-MCPDEs 的加标回收率在 80%∼110%范围内。结果表明,GEs 和 3-MCPDEs 在食品中几乎无处不在(95%),浓度最高的是加工脂肪,其次是饼干和涂抹酱。含棕榈油的食品含有更高水平的污染物(p<0.05),高达 58.1%的含棕榈油食品的 GEs 或 3-MCPDEs 含量超过欧盟设定的上限。饼干和方便面被确定为 GEs 和 3-MCPDEs 的主要暴露源,儿童(0 岁至 12 岁)的潜在日摄入量超过可耐受日摄入量。

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