Master Program in Food Safety, College of Nutrition, Taipei Medical University, Taipei, Taiwan.
School of Food Safety, College of Nutrition, Taipei Medical University, Taipei, Taiwan.
Food Chem. 2024 Jan 1;430:137055. doi: 10.1016/j.foodchem.2023.137055. Epub 2023 Jul 31.
Glycidyl esters (GEs) and 3-monochloropropane-1,2-diol esters (3-MCPDEs) are carcinogenic contaminants found in refined oils. This study aimed to determine levels of GEs and 3-MCPDEs in packaged foodstuffs, and estimate daily exposure levels using food consumption data. The analysis involved Soxtec extraction and gas chromatography-mass spectrometry, and the recovery of spiked GEs and 3-MCPDEs was within the range of 80%∼110%. Results showed that GEs and 3-MCPDEs were almost ubiquitous in food products (95%), with the highest concentrations found in processed fats, followed by cookies and spreads. Food products containing palm-derived oils had significantly higher levels of contaminants (p < 0.05), with up to 58.1% of palm oil-containing foodstuffs exceeding the upper limits of either GEs or 3-MCPDEs set by the European Union. Cookies and instant noodles were identified as the main sources of exposure to GEs and 3-MCPDEs, with potential daily intake levels exceeding the tolerable daily intakes in children aged 0 ∼ 12 years.
缩水甘油酯(GEs)和 3-单氯丙二醇酯(3-MCPDEs)是精炼油中发现的致癌污染物。本研究旨在测定包装食品中 GEs 和 3-MCPDEs 的含量,并利用食物消费数据评估每日摄入量。分析采用 Soxtec 提取和气相色谱-质谱法,GEs 和 3-MCPDEs 的加标回收率在 80%∼110%范围内。结果表明,GEs 和 3-MCPDEs 在食品中几乎无处不在(95%),浓度最高的是加工脂肪,其次是饼干和涂抹酱。含棕榈油的食品含有更高水平的污染物(p<0.05),高达 58.1%的含棕榈油食品的 GEs 或 3-MCPDEs 含量超过欧盟设定的上限。饼干和方便面被确定为 GEs 和 3-MCPDEs 的主要暴露源,儿童(0 岁至 12 岁)的潜在日摄入量超过可耐受日摄入量。