State Key Joint Laboratory of Environmental Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China.
State Key Laboratory of Earth Surface Processes and Resource Ecology, Faculty of Geographical Science, Beijing Normal University, Beijing 100875, China.
J Hazard Mater. 2023 Oct 5;459:132181. doi: 10.1016/j.jhazmat.2023.132181. Epub 2023 Jul 28.
Atmospheric heavy metal (HM) pollution may pose a significant threat to the fragile ecosystem of Qinghai-Tibet Plateau (QTP). To investigate potential atmospheric HM pollution within the QTP region of China, mosses, along with other higher plants and soil, were collected from 33 sites for heavy metal measurement. The concentration ranges of Zn, Pb, Cd, and Cu in mosses were 6.07-69.9, 5.36-23.9, 0.60-1.05, and 14.4-50.5 mg·kg (dry weight), respectively, significantly higher than those in other higher plants, except for Zn. The spatial distribution of relative concentrations (RCs; moss to top soil) of HMs varied considerably, indicating distinct differences in atmospheric Zn and Cu pollution levels between the northern and southern QTP. This study first reported that moderate regional atmospheric Cu pollution, primarily due to large-scale mining in recent years, had occurred, particularly in southern QTP. Pb also presented slight pollution due to anthropogenic activities. However, Cd showed almost no atmospheric pollution, while Zn concentrations were relatively high in southern QTP. Although less severe than atmospheric pollution levels in Chinese inland or coastal cities, the atmospheric pollution of Pb and Cu in QTP indicated by mosses were far more severe than global background areas, or even worse than most European cities.
大气重金属(HM)污染可能对青藏高原(QTP)脆弱的生态系统构成重大威胁。为了调查中国 QTP 地区潜在的大气 HM 污染,采集了 33 个地点的苔藓、其他高等植物和土壤进行重金属测量。苔藓中 Zn、Pb、Cd 和 Cu 的浓度范围分别为 6.07-69.9、5.36-23.9、0.60-1.05 和 14.4-50.5 mg·kg(干重),明显高于其他高等植物,除了 Zn。HM 的相对浓度(RC;苔藓与顶层土壤)的空间分布差异很大,表明 QTP 北部和南部大气 Zn 和 Cu 污染水平存在明显差异。本研究首次报道,由于近年来大规模采矿,该地区已发生中等程度的区域性大气 Cu 污染,尤其是在 QTP 南部。由于人为活动,Pb 也呈现出轻微污染。然而,Cd 几乎没有大气污染,而 Zn 浓度在 QTP 南部相对较高。尽管 QTP 大气 Pb 和 Cu 的污染程度不如中国内陆或沿海城市严重,但苔藓所指示的 QTP 大气污染比全球背景地区甚至比大多数欧洲城市更为严重。