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在1500勒克斯光照下效率为25.53%的室内光伏纤维。

Indoor Photovoltaic Fiber with an Efficiency of 25.53% under 1500 Lux Illumination.

作者信息

Zhu Zhengfeng, Lin Zhengmeng, Zhai Weijie, Kang Xinyue, Song Jiatian, Lu Chenhao, Jiang Hongyu, Chen Peining, Sun Xuemei, Wang Bingjie, Wang Zhong-Sheng, Peng Huisheng

机构信息

State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science and Laboratory of Advanced Materials, Fudan University, Shanghai, 200438, China.

Department of Chemistry, Fudan University, Shanghai, 200438, China.

出版信息

Adv Mater. 2024 Mar;36(11):e2304876. doi: 10.1002/adma.202304876. Epub 2023 Dec 24.

Abstract

Photovoltaic devices represent an efficient electricity generation mode. Integrating them into textiles offers exciting opportunities for smart electronic textiles-with the ultimate goal of supplying power for wearable technology-which is poised to change how electronic devices are designed. Many human activities occur indoors, so realizing indoor photovoltaic fibers (IPVFs) that can be woven into textiles to power wearables is critical, although currently unavailable. Here, a dye-sensitized IPVF is constructed by incorporating titanium dioxide nanoparticles into aligned nanotubes to produce close contact and stable interfaces among active layers on a curved fiber substrate, thus presenting efficient charge transport and low charge recombination in the photoanode. With the combination of highly conductive core-sheath Ti/carbon nanotube fiber as a counter electrode, the IPVF shows a certified power conversion efficiency of 25.53% under 1500 lux illuminance. Its performance variation is below 5% after bending, twisting, or pressing for 1000 cycles. These IPVFs are further integrated with fiber batteries as self-charging power textiles, which are demonstrated to effectively supply electricity for wearables, solving the power supply problem in this important direction.

摘要

光伏器件是一种高效的发电方式。将其集成到纺织品中为智能电子纺织品带来了令人兴奋的机遇,其最终目标是为可穿戴技术供电,这有望改变电子设备的设计方式。许多人类活动发生在室内,因此实现可编织到纺织品中以为可穿戴设备供电的室内光伏纤维(IPVF)至关重要,尽管目前尚无法实现。在此,通过将二氧化钛纳米颗粒掺入排列的纳米管中,在弯曲的纤维基板上的活性层之间产生紧密接触和稳定界面,从而构建了一种染料敏化IPVF,进而在光阳极中实现了高效的电荷传输和低电荷复合。通过将高导电性的芯鞘Ti/碳纳米管纤维用作对电极,该IPVF在1500勒克斯照度下的认证功率转换效率为25.53%。在弯曲、扭转或按压1000次循环后,其性能变化低于5%。这些IPVF进一步与纤维电池集成,形成自充电电力纺织品,经证明可为可穿戴设备有效供电,在这一重要方向上解决了电源问题。

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