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锕系元素前三个光谱的原子数据更新

Update of Atomic Data for the First Three Spectra of Actinium.

作者信息

Kramida Alexander

机构信息

National Institute of Standards and Technology, Gaithersburg, MD 20899, USA.

出版信息

Atoms. 2022 Apr 22;10(2). doi: 10.3390/atoms10020042.

DOI:10.3390/atoms10020042
PMID:37551336
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10405742/
Abstract

The present article describes a complete reanalysis of all published data on observed spectral lines and energy levels of the first three spectra of actinium (Ac I-III). In Ac I, three previously determined energy levels have been rejected, 12 new energy levels have been found; for six previously known levels, either the values or the energies have been revised, and the ionization energy has been redetermined with an improved accuracy. In the line list of Ac I, three previous classifications have been discarded, 16 new ones have been found, and three have been revised. In Ac II, 16 new energy levels have been established, and 36 new identifications have been found for previously observed but unclassified lines. In both Ac I and Ac II, new sets of transition probabilities have been calculated. For all three spectra, complete datasets of critically evaluated energy levels, observed lines, and transition probabilities have been constructed to serve as recommended data on these spectra.

摘要

本文描述了对所有已发表的关于锕(Ac I - III)前三光谱的观测谱线和能级数据的全面重新分析。在Ac I中,三个先前确定的能级已被舍弃,发现了12个新的能级;对于六个先前已知的能级,其 值或能量已被修正,并且电离能已以更高的精度重新确定。在Ac I的谱线列表中,三个先前的分类已被摒弃,发现了16个新的分类,并且三个已被修正。在Ac II中,建立了16个新的能级,并且为先前观测但未分类的谱线发现了36个新的识别。在Ac I和Ac II中,都计算了新的跃迁概率集。对于所有三个光谱,已构建了经过严格评估的能级、观测谱线和跃迁概率的完整数据集,以作为关于这些光谱的推荐数据。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6e6/10405742/56f2c0b6e958/nihms-1914401-f0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6e6/10405742/47d31477d137/nihms-1914401-f0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6e6/10405742/9f050fab9f57/nihms-1914401-f0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6e6/10405742/3d28cd88db19/nihms-1914401-f0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6e6/10405742/df97c66a3c6d/nihms-1914401-f0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6e6/10405742/d5c3cb90d9eb/nihms-1914401-f0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6e6/10405742/56f2c0b6e958/nihms-1914401-f0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6e6/10405742/47d31477d137/nihms-1914401-f0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6e6/10405742/9f050fab9f57/nihms-1914401-f0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6e6/10405742/3d28cd88db19/nihms-1914401-f0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6e6/10405742/df97c66a3c6d/nihms-1914401-f0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6e6/10405742/d5c3cb90d9eb/nihms-1914401-f0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6e6/10405742/56f2c0b6e958/nihms-1914401-f0006.jpg

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本文引用的文献

1
Detection of the Lowest-Lying Odd-Parity Atomic Levels in Actinium.锕中最低激发态奇宇称原子能级的探测
Phys Rev Lett. 2020 Aug 14;125(7):073001. doi: 10.1103/PhysRevLett.125.073001.
2
Towards high-resolution laser ionization spectroscopy of the heaviest elements in supersonic gas jet expansion.朝向超音速气流膨胀中最重元素的高分辨率激光电离光谱学。
Nat Commun. 2017 Feb 22;8:14520. doi: 10.1038/ncomms14520.
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Assessing Uncertainties of Theoretical Atomic Transition Probabilities with Monte Carlo Random Trials.用蒙特卡罗随机试验评估理论原子跃迁概率的不确定性
Atoms. 2014 Jun;2(2):86-122. doi: 10.3390/atoms2020086. Epub 2014 Apr 14.
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Optical transitions in highly charged californium ions with high sensitivity to variation of the fine-structure constant.高电荷态 Californium 离子的光学跃迁,对精细结构常数的变化具有高灵敏度。
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