Kramida Alexander
National Institute of Standards and Technology, Gaithersburg, MD 20899.
J Res Natl Inst Stand Technol. 2013 Apr 15;118:168-98. doi: 10.6028/jres.118.009. eCollection 2013.
All available experimental measurements of the spectrum of the Ag(+) ion are critically reviewed. Systematic shifts are removed from the measured wavelengths. The compiled list of critically evaluated wavelengths is used to derive a comprehensive list of energy levels with well-defined uncertainties. Eigenvector compositions and level designations are found in two alternate coupling schemes. Some of the older work is found to be incorrect. A revised value of the ionization energy, 173283(7) cm(-1), equivalent to 21.4844(8) eV, is derived from the new energy levels. A set of critically evaluated transition probabilities is given.
对所有可得的Ag(+)离子光谱的实验测量进行了严格审查。从测量波长中消除了系统偏差。经严格评估的波长汇编列表用于推导具有明确不确定性的综合能级列表。在两种交替耦合方案中找到了本征向量组成和能级指定。发现一些早期的工作存在错误。从新的能级推导出电离能的修订值为173283(7) cm(-1)，相当于21.4844(8) eV。给出了一组经严格评估的跃迁概率。
