Radzhabov Amirbek D, Soldatova Natalia S, Ivanov Daniil M, Yusubov Mekhman S, Kukushkin Vadim Yu, Postnikov Pavel S
Research School of Chemistry and Applied Biomedical Sciences, Tomsk Polytechnic University, Tomsk 634050, Russian Federation.
Institute of Chemistry, Saint Petersburg State University, Saint Petersburg 199034, Russian Federation.
Org Biomol Chem. 2023 Aug 23;21(33):6743-6749. doi: 10.1039/d3ob00833a.
We developed an atom- and reaction mass efficient strategy for the preparation of diarylselenides using iodonium salts as reactants. The developed approach allows the obtaining of diarylselenides from the corresponding trimethoxyphenyl-substituted iodonium salts a two-step one-pot reaction sequence. The proposed metal-free methodology is based on the involvement of both iodonium aryl groups for diarylation.
我们开发了一种以碘鎓盐为反应物，原子和反应质量高效的二芳基硒醚制备策略。所开发的方法允许通过两步一锅反应序列从相应的三甲氧基苯基取代的碘鎓盐中获得二芳基硒醚。所提出的无金属方法基于碘鎓芳基用于双芳基化的参与。
