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采用硒纳米颗粒增强松木和山毛榉木材的颜色和抗菌性能的新方法。

A novel approach for enhancing the color and antimicrobial properties of pine and beech wood using Se-NPs.

机构信息

Department of Textile Printing, Dyeing and Finishing, Faculty of Applied Arts, Damietta University, Damietta, 34512, Egypt.

Department of Interior Design and Furniture, Faculty of Applied Arts, Damietta University, Damietta, 34512, Egypt.

出版信息

Sci Rep. 2023 Aug 10;13(1):12972. doi: 10.1038/s41598-023-39748-5.

Abstract

Pine wood (PW) and beech wood (BW) are the most used wood in furniture and other applications owing to their unique characteristics and low machining cost. However, their biodegradability and varied moisture content limit their wider use and durability. Therefore, in this study, nanotechnology was used as a novel eco-friendly approach to enhance the durability, antimicrobial properties, and color of wood. Selenium nanoparticles (Se-NPs) were prepared in spherical shape at varied concentrations (25 and 50 mM) using an eco-friendly method in the range of 35-80 and 40-155 nm, respectively. Se-NPs formation at the nanoscale was confirmed using UV/Vis analysis, transmission electron microscopy (TEM), and X-ray diffraction (XRD). The prepared Se-NPs were then impregnated into PW and BW for different periods ranging from 2 h to 1 week. The treated wood were then leached in distilled water for 14 days to eliminate excess Se-NPs from the wood surface. The treated wood surfaces were examined using energy-dispersive X-ray spectroscopy (EDX) and scanning electron microscopy (SEM). In addition, the depth of Se-NPs penetration into the treated wood at both tangential and radial sides was determined. Se-NPs impacts on the color properties, density, moisture content and antimicrobial activities of the treated wood were evaluated. PW treated with Se-NPs showed better antimicrobial and color characteristics than treated BW. PW samples immersed in 50 mM Se-NPs for 2 h showed the highest K/S values, whereas the highest antimicrobial values were obtained for those immersed at the same concentration for 2 days, and 1 week.

摘要

松木(PW)和山毛榉木(BW)由于其独特的特性和低廉的加工成本,是家具和其他应用中最常用的木材。然而,它们的生物降解性和多变的含水量限制了它们更广泛的使用和耐久性。因此,在本研究中,纳米技术被用作一种新颖的环保方法来提高木材的耐久性、抗菌性能和颜色。使用环保方法在 35-80 和 40-155nm 的范围内分别制备出浓度为 25 和 50mM 的球形硒纳米颗粒(Se-NPs)。使用紫外/可见分析、透射电子显微镜(TEM)和 X 射线衍射(XRD)确认了纳米级 Se-NPs 的形成。然后将制备的 Se-NPs 浸渍到 PW 和 BW 中不同的时间段,从 2h 到 1 周不等。然后将处理过的木材在蒸馏水中浸出 14 天,以消除木材表面多余的 Se-NPs。用能量色散 X 射线光谱(EDX)和扫描电子显微镜(SEM)检查处理过的木材表面。此外,还确定了 Se-NPs 在处理过的木材的径向和切向两侧的渗透深度。评估了 Se-NPs 对处理过的木材颜色特性、密度、水分含量和抗菌活性的影响。用 Se-NPs 处理的 PW 表现出比处理的 BW 更好的抗菌和颜色特性。在 50mM Se-NPs 中浸泡 2h 的 PW 样品显示出最高的 K/S 值,而在相同浓度下浸泡 2 天和 1 周的样品则表现出最高的抗菌值。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f93c/10415366/d23972f9e063/41598_2023_39748_Fig1_HTML.jpg

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