An appraisal of trace element concentration and environmental risk of sediments: a baseline study of sediments from Arasalar River Estuary, Tamil Nadu, India.

A total of 21 surface sediment samples collected from Arasalar River are subjected to sediment texture (sand-silt-clay ratio), trace elements, organic matter, and CaCO studies to understand the accumulation dynamics of sediments. To assess the impact of metal pollution in estuarine sediments, the essential parameters should be done by checking the sediment characteristics, spatial distribution of heavy metal sources, sediment dynamics, and geochemical analysis. To evaluate the contamination level of metal pollution, a basic standard reference is required to decipher the values ranging from natural to anthropogenic contribution. From this research analysis, it is observed that the study area predominantly comprises silty sand and sand silty nature. The calcium carbonate content in the sediment is found to be proportional to the presence of shell fragments, whereas the organic matter (OM) is derived from riverine and coastal input which acts as a primary source. The obtained results confessed the average contents (mg/g) for the following selected eight elements in the order of Fe (35249-49068) > Mn (286-519) > Ni (107-279) > Cu (78.30-155.70) > Cr (50-99) > Zn (38.70-91.90) > Pb (39.90-62.40), and Co (12.6-29.1) by using an atomic absorption spectrophotometer (AAS) are utilized for this analysis. Multivariate analysis of heavy metals affirms geogenic sources (weathering of parent rocks) for Fe, Mn, Cr, Co, and Zn, whereas Cu, Ni, and Pb originated from anthropogenic activities (urban and industrial activities). The pollution load index, sediment pollution index, I index, and PERI are categorized as under polluted, low to moderate polluted, and low potential environmental risk variety. Constant inspection and guidance are needed to prevent effluences from various agriculture and industrial activities in the nearby regions. The findings from this research may support and help the government to follow the suitable remediation on the better management of river and coastal areas.