Ivanov Evgenii N, Almeida-Marrero Verónica, Koifman Oskar I, Aleksandriiskii Viktor V, Torres Tomas, Islyaikin Mikhail K
IRLoN, Research Institute of Macroheterocycles, Ivanovo State University of Chemistry and Technology, 7, Sheremetievskiy Ave., 153000 Ivanovo, Russia.
G. A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 1 Akademicheskaya Str., 153045 Ivanovo, Russia.
Molecules. 2023 Jul 29;28(15):5740. doi: 10.3390/molecules28155740.
New substituted [30]trithiadodecaazahexaphyrines (hemihexaphyrazines) were synthesized by a crossover condensation of 2,5-diamino-1,3,4-thiadiazole with 4-chloro-5-(2,6-diisopropylphenoxy)- or 4,5-bis-(2,6-diisopropylphenoxy)phthalonitriles. The compounds were characterized by H-, C-NMR, including COSY, HMBC, and HSQC spectroscopy, MALDI TOF spectrometry, elemental analysis, IR and UV-Vis absorbance and fluorescence techniques.
通过2,5-二氨基-1,3,4-噻二唑与4-氯-5-(2,6-二异丙基苯氧基)-或4,5-双-(2,6-二异丙基苯氧基)邻苯二甲腈的交叉缩合反应合成了新型取代的[30]三硫杂十二氮杂六卟啉（半六卟嗪）。通过H-、C-NMR（包括COSY、HMBC和HSQC光谱）、MALDI TOF光谱、元素分析、红外光谱以及紫外-可见吸收和荧光技术对这些化合物进行了表征。
