含2,6-二异丙基苯氧基的大位阻取代半六氮杂苯的合成与表征
Synthesis and Characterization of Bulky Substituted Hemihexaphyrazines Bearing 2,6-Diisopropylphenoxy Groups.
作者信息
Ivanov Evgenii N, Almeida-Marrero Verónica, Koifman Oskar I, Aleksandriiskii Viktor V, Torres Tomas, Islyaikin Mikhail K
机构信息
IRLoN, Research Institute of Macroheterocycles, Ivanovo State University of Chemistry and Technology, 7, Sheremetievskiy Ave., 153000 Ivanovo, Russia.
G. A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 1 Akademicheskaya Str., 153045 Ivanovo, Russia.
出版信息
Molecules. 2023 Jul 29;28(15):5740. doi: 10.3390/molecules28155740.
New substituted [30]trithiadodecaazahexaphyrines (hemihexaphyrazines) were synthesized by a crossover condensation of 2,5-diamino-1,3,4-thiadiazole with 4-chloro-5-(2,6-diisopropylphenoxy)- or 4,5-bis-(2,6-diisopropylphenoxy)phthalonitriles. The compounds were characterized by H-, C-NMR, including COSY, HMBC, and HSQC spectroscopy, MALDI TOF spectrometry, elemental analysis, IR and UV-Vis absorbance and fluorescence techniques.
通过2,5-二氨基-1,3,4-噻二唑与4-氯-5-(2,6-二异丙基苯氧基)-或4,5-双-(2,6-二异丙基苯氧基)邻苯二甲腈的交叉缩合反应合成了新型取代的[30]三硫杂十二氮杂六卟啉（半六卟嗪）。通过H-、C-NMR（包括COSY、HMBC和HSQC光谱）、MALDI TOF光谱、元素分析、红外光谱以及紫外-可见吸收和荧光技术对这些化合物进行了表征。
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