Department of Chemistry & Biochemistry, Fort Lewis College, 1000 Rim Drive, Durango, CO 81301, USA.
Ska Brewing Company, 225 Girard St., Durango, CO 81303, USA.
Molecules. 2023 Aug 1;28(15):5802. doi: 10.3390/molecules28155802.
Hops are among the most costly and environmentally impactful raw materials used in brewing, yet they play a crucial role in the aroma of beer. However, predicting beer aroma based on hop variety or hopping method remains arduous. This is partly because hop oils are unique for each hop variety, and they may be biotransformed by yeast enzymes during fermentation. Even slight molecular structure modifications can dramatically affect the organoleptic properties of beer. Through combined chemical and sensory analysis of dry-hopped beers prepared with different hop varieties (Azacca, Idaho-7, and Sultana), this work aimed to profile the aromas and the overall biotransformation processes taking place during fermentation. A total of 51 volatile organic compounds (VOCs) were semi-quantified and monitored: 19 esters, 13 sesquiterpenes, 7 ketones, 7 alcohols, 4 monoterpenes, and 1 volatile acid. There were significant similarities in the measured analytes and perceived aromas of these beers, but one hop variety (Sultana) delivered an increased quantity of unique aromas and an increased concentration of volatiles in the headspace for the same quantity of hop pellets added. This work provides practical information to brewers who utilize hops in beer production.
啤酒花是酿造中最昂贵和对环境影响最大的原材料之一,但它在啤酒的香气中起着至关重要的作用。然而,基于啤酒花品种或添加方式预测啤酒香气仍然很困难。部分原因是每个啤酒花品种的啤酒花油都是独特的,并且它们可能在发酵过程中被酵母酶生物转化。即使是微小的分子结构修饰也会极大地影响啤酒的感官特性。本研究通过对使用不同啤酒花品种(阿扎卡、爱达荷 7 号和苏丹娜)制备的干投啤酒进行化学和感官综合分析,旨在对香气和发酵过程中发生的整体生物转化过程进行分析。共半定量和监测了 51 种挥发性有机化合物(VOC):19 种酯类、13 种倍半萜、7 种酮类、7 种醇类、4 种单萜类和 1 种挥发性酸。这些啤酒在测量的分析物和感知的香气方面具有显著的相似性,但有一种啤酒花品种(苏丹娜)在添加相同数量的啤酒花颗粒时,提供了更多独特的香气和更高浓度的挥发性物质。这项工作为在啤酒生产中使用啤酒花的酿酒师提供了实用信息。