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玻璃纤维增强塑料(GFRP)和碳纤维增强塑料(CFRP)筋材在采用淡水或海水制成的硫铝酸钙水泥混凝土孔隙溶液中的耐久性

Durability of GFRP and CFRP Bars in the Pore Solution of Calcium Sulfoaluminate Cement Concrete Made with Fresh or Seawater.

作者信息

Wang Tuanjie, Razaqpur Abdul Ghani, Chen Shaoliang

机构信息

Sino-Canada Joint R&D Centre on Water and Environmental Safety, College of Environmental Science and Engineering, Nankai University, Tianjin 300350, China.

College of Civil Engineering, Zhengzhou University of Industrial Technology, Zhengzhou 451150, China.

出版信息

Polymers (Basel). 2023 Aug 4;15(15):3306. doi: 10.3390/polym15153306.

Abstract

Calcium sulfoaluminate cement concrete (CSAC) reinforced by fiber-reinforced polymer (FRP) bars, termed bars for brevity, is a good alternative to steel-reinforced concrete in marine environments due to the corrosion resistance of FRP and the lower pH of CSAC. For the first time, multi-mechanical tests are conducted to compare the durability of glass FRP (GFRP) to that of carbon FRP (CFRP) after exposure to CSAC pore solution. The bars were immersed in a simulated pore solution of CSAC made with either fresh water and river sand or with seawater and sea sand. Solution temperature was held constant at 30 °C, 45 °C or 60 °C for 30, 60, 90 and 180 days of immersion. Tensile, horizontal and transverse shear tests, as well as detailed microstructural analyses, were conducted to determine the level and mechanisms of degradation for each type of bar. Sea salt increases the degradation of both bars, but it degrades GFRP more than CFRP. The bars' retained tensile strength is a reliable indicator of their durability, while their post-exposure horizontal and transverse shear strengths are found inconsistent and counter intuitive. In the GFRP, the fiber, the epoxy matrix and their interface suffered damage, but in the CFRP, the carbon fiber was not damaged. Under the test conditions in this study, the maximum reduction in the tensile strength of the GFRP was 56.9% while that of CFRP was 15.1%. Based on the relevant ASTM standard, the CFRP bar satisfies the alkaline resistance requirement of the standard in the CSAC pore solution with and without salt, whereas the GFRP bar does not meet the same requirement in the above pore solution with salt.

摘要

由纤维增强聚合物(FRP)筋增强的硫铝酸钙水泥混凝土(CSAC),简称为筋,由于FRP的耐腐蚀性和CSAC较低的pH值,在海洋环境中是钢筋混凝土的良好替代品。首次进行了多项力学试验,以比较玻璃纤维增强塑料(GFRP)和碳纤维增强塑料(CFRP)在暴露于CSAC孔隙溶液后的耐久性。将筋浸泡在由淡水和河砂或海水和海砂制成的CSAC模拟孔隙溶液中。溶液温度保持在30℃、45℃或60℃恒定,浸泡30、60、90和180天。进行拉伸、水平和横向剪切试验以及详细的微观结构分析,以确定每种筋的降解程度和机制。海盐会增加两种筋的降解,但对GFRP的降解比对CFRP的降解更大。筋的保留抗拉强度是其耐久性的可靠指标,而其暴露后的水平和横向剪切强度则不一致且与直觉相反。在GFRP中,纤维、环氧树脂基体及其界面受到了损伤,但在CFRP中,碳纤维没有受损。在本研究的试验条件下,GFRP的抗拉强度最大降低了56.9%,而CFRP的抗拉强度最大降低了15.1%。根据相关的ASTM标准,CFRP筋在有盐和无盐的CSAC孔隙溶液中均满足标准的耐碱性要求,而GFRP筋在上述有盐的孔隙溶液中不满足相同要求。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9ee5/10422602/261d6a4dcb20/polymers-15-03306-g009.jpg

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