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采用高效液相色谱-光电二极管阵列和质谱联用检测法测定三种虾废料中的虾青素和虾青素酯。

Determination of astaxanthin and astaxanthin esters in three samples of shrimp waste () by high performance liquid chromatography coupled photo-diode array and mass spectrometry detection.

机构信息

Laboratory of Materials-Catalysis, Chemistry Department, Faculty of Sciences of Tetouan, Abdelmalek Essaadi University, Tetouan, Morocco.

Department of Chemical Biological, Pharmaceutical and Environmental Sciences, University of Messina, Messina, Italy.

出版信息

Nat Prod Res. 2024 Aug;38(16):2901-2908. doi: 10.1080/14786419.2023.2245959. Epub 2023 Aug 12.

DOI:10.1080/14786419.2023.2245959
PMID:37572009
Abstract

The present study aimed to identify the content of astaxanthin and its esterified forms using high-performance liquid chromatography coupled with diode array and atmospheric pressure chemical ionisation mass spectrometry detection in three samples of shrimp waste. The analyses revealed twenty-one astaxanthin derivatives, including astaxanthin in free form, across all three extracts with the highest number of derivatives observed in the head extract. The shell extract had a lower content of astaxanthin and its esterified forms, with monoesterified astaxanthins being the major components, with contents ranging from 0.5-1 mg g. On the other hand, in both global waste and head extracts, astaxanthin diesters were found to be the dominant bioactive compounds, with contents ranging from 0.7-5.2 mg g and 10.2-18.2 mg g, respectively. Notably, the astaxanthin content extracted from head was significantly higher compared to other extracts, indicating its potential as a valuable source of bioactive compounds.

摘要

本研究旨在通过高效液相色谱-二极管阵列-大气压化学电离质谱联用检测三种虾废料样品,鉴定虾青素及其酯化形式的含量。分析表明,三种提取物中共发现二十一种虾青素衍生物,包括游离虾青素,其中头部提取物中观察到的衍生物数量最多。壳提取物中虾青素及其酯化形式的含量较低,以单酯化虾青素为主,含量在 0.5-1mg/g 之间。另一方面,在全球废物和头部提取物中,虾青素二酯被发现是主要的生物活性化合物,含量分别在 0.7-5.2mg/g 和 10.2-18.2mg/g 之间。值得注意的是,从头部提取的虾青素含量明显高于其他提取物,表明其作为生物活性化合物有价值的来源的潜力。

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