A Preference for Heterolepticity - Schlenk Type Equilibria in Organometallic Beryllium Systems.
作者信息
Buchner Magnus R, Thomas-Hargreaves Lewis R, Berthold Chantsalmaa, Bekiş Deniz F, Ivlev Sergei I
机构信息
Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße 4, 35032, Marburg, Germany.
出版信息
Chemistry. 2023 Oct 26;29(60):e202302495. doi: 10.1002/chem.202302495. Epub 2023 Sep 27.
PMID:37575053
Abstract
The reaction of homoleptic beryllium halide with diphenyl beryllium complexes leads to the clean formation of heteroleptic beryllium Grignard compounds [(L) BePhX] (X=Cl, Br, I; L=C-, N-, O-donor ligand). The influence of ligands and solvent on these compounds, their formation and exchange equilibria in solution were investigated, together with the factors determining the complex constitution.
摘要
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